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Poly-phenylene jacketed tailor-made dendritic phenylazomethine ligand for nanoparticle synthesis.
Chem Sci
May 2022
Laboratory for Chemistry and Life Science (CLS), Institute of Innovative Research (IIR), Tokyo Institute of Technology Yokohama 226-8503 Japan
Synthesizing metal clusters with a specific number of atoms on a preparative scale for studying advanced properties is still a challenge. The dendrimer templated method is powerful for synthesizing size or atomicity controlled nanoparticles. However, not all atomicity is accessible with conventional dendrimers.
View Article and Find Full Text PDFPolyphenylenepyridyl dendrimers as stabilizing and controlling agents for CdS nanoparticle formation.
Nanoscale
April 2012
A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St., Moscow, 119991, Russia.
Semiconductor nanoparticles (NPs) are being actively explored for applications in medical diagnostics and therapy and numerous electronic devices including solar cells. In this paper we demonstrate the influence of the third generation rigid polyphenylenepyridyl dendrimers (PPPDs) of a different architecture on the formation of well-defined CdS NPs. A high temperature approach to the synthesis of novel CdS/PPPD nanocomposites is feasible due to the high thermal stability of PPPDs.
View Article and Find Full Text PDFNoncoordinating Dendrimer Polyanions: Cocatalysts for the Metallocene-Catalyzed Olefin Polymerization.
Angew Chem Int Ed Engl
May 2001
Bayer AG ZSB Zentrale Forschung, Materialforschung Gebäude Q 18, 51368 Leverkusen (Germany).
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