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Synthesis of Butterfly-Like Shaped Gold Nanomaterial: For the Regulation of Liquid-Liquid Phase-Separated Biomacromolecule Droplets.
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December 2023
Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki, 305-8573, Japan.
Nanotechnology is a critical tool to manipulate the sophisticated behavior of biological structures and has provided new research fields. Liquid-liquid phase-separated (LLPS) droplets gather attention as basic reaction fields in a living cell. Droplets play critical roles in regulating protein behavior, including enzyme compartmentalization, stress response, and disease pathogenesis.
View Article and Find Full Text PDFConcave Butterfly-Shaped Organometallic Hydrocarbons? U.H.F.B. and M.L. thank the NSF for generous support (CAREER, CHE 9981765, 2000-2004). U.H.F.B. is Camille Dreyfus Teacher-Scholar (2000-2004).
Angew Chem Int Ed Engl
April 2001
Department of Chemistry and Biochemistry The University of South Carolina Columbia, SC 29208 (USA) Fax (+1) 803-777-9521.
Concave Butterfly-Shaped Organometallic Hydrocarbons?
Angew Chem Int Ed Engl
April 2001
Department of Chemistry and Biochemistry The University of South Carolina Columbia, SC 29208 (USA) Fax (+1) 803-777-9521.
A metamorphosis of the tetraethynyl precursor 1 through double Cu-catalyzed ring closure leads to the corresponding butterfly-shaped cyclobutadiene complexes 2 in high yield (94 %). Single-crystal X-ray diffraction shows that the large organic ligand is distinctly nonplanar with a concave topology. Cp=cyclopentadiene.
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