Preflocculated ferric hydroxide flocs were subjected to either a simple shear flow or a two-dimensional straining flow, and their motion was optically observed. Digital image analysis was applied to extract information on orientation and deformation from the digitized frames. It was found that the simple shear flow led to a rotation of the flocs whose motion can be understood from the behavior of a solid ellipsoid. In the extensional flow, no continuous rotation occurred and flocs were broken apart along the axis of straining. The rupture forces estimated from an ellipsoid model were found to be in the range of 0.1 N/m(2). Copyright 2000 Academic Press.
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http://dx.doi.org/10.1006/jcis.1999.6671 | DOI Listing |
RSC Adv
January 2025
Univ. Grenoble Alpes, CNRS, CERMAV 38000 Grenoble France
Supramolecular oleogels, in which low-molecular weight oleogelators self-assemble into various nanostructures through non-covalent interactions, have witnessed increasing research activity in various fields of science, including food, cosmetics or remediation of marine oil spills. Herein, we report a simple scalable and environmentally friendly carbohydrate-based oleogelator, namely, the sodium salt of ,'-dimethyl β- glucosyl barbiturate (GlcBMe) that self-assembles through sonication to induce the gelation of polar organic solvent and later of non-polar vegetable oils by cationic exchange with quaternary ammonium surfactants. Water-soluble GlcBMe was capable of forming self-assembled fibrillar network bridging insoluble particles in the oil by sonication in the presence of a small amount of water.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
CPT, CNRS, Aix Marseille Univ, Université de Toulon, (UMR 7332), Turing Center for Living Systems, Marseille, France.
Athermal (i.e., zero-temperature) underconstrained systems are typically floppy, but they can be rigidified by the application of external strain, which is theoretically well understood.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
State Key Lab of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
Mechanoresponsive colloidal photonic crystals embedded in elastic solid matrices exhibit tunable optical properties under mechanical force, showing great potential for various applications. However, the response of colloidal crystals embedded in a liquid matrix remains largely unexplored. In this study, we investigate the structural and optical transitions of colloidal crystals composed of particles suspended in a liquid oligomer under pressing and shear forces.
View Article and Find Full Text PDFPharmaceutics
December 2024
Drug Product Development, Continuus Pharmaceuticals, Woburn, MA 01801, USA.
In recent years, with the increasing patient population, the need for complex and patient-centric medications has increased enormously. Traditional manufacturing techniques such as direct blending, high shear granulation, and dry granulation can be used to develop simple solid oral medications. However, it is well known that "one size fits all" is not true for pharmaceutical medicines.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Department of Engineering, University of Palermo, Viale delle Scienze, Edificio 6, 90128 Palermo, Italy.
This paper deals with the design of novel epoxy adhesives by incorporating thermoplastic polymers such as polyetherimide (PEI) and poly(ε-caprolactone) (PCL) into a bio-based and recyclable epoxy resin, known as Polar Bear. The adhesives were characterized by their mechanical (quasi-static and dynamic) and rheological properties, thermal stability, and adhesion properties in single-lap joints tested at three different temperatures (i.e.
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