Chemical syntheses of 2'-O-(allyloxycarbonyl)methyladenosine, 2'-O-(methoxycarbonyl)methyladenosine and 2'-O-(2,3-dibenzoyloxy)propyluridine 3'-2-cyanoethyl-N,N-diisopropyl phosphoramidite building blocks are described. These monomers were used successfully to incorporate carboxylic acid, 1,2-diol and aldehyde functionalities into synthetic oligonucleotides.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1080/15257770008045453 | DOI Listing |
Nano Lett
January 2025
Synergetic Extreme Condition High-Pressure Science Center, State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, China.
Covalent-organic frameworks (COFs) are dynamic covalent porous organic materials constructed from emissive molecular organic building blocks. However, most two-dimensional (2D) COFs are nonemissive or weakly emissive in the solid state owing to the intramolecular rotation and vibration together with strong π-π interactions. Herein, we report a pressure strategy to achieve the bright multicolor emission from yellow to red in the 2D triazine triphenyl imine COF (TTI-COF).
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan.
The development of hole-collecting materials is indispensable to improving the performance of perovskite solar cells (PSCs). To date, several anchorable molecules have been reported as effective hole-collecting monolayer (HCM) materials for p-i-n PSCs. However, their structures are limited to well-known electron-donating skeletons, such as carbazole, triarylamine, etc.
View Article and Find Full Text PDFCurr Opin Biotechnol
January 2025
INM - Leibniz Institute for New Materials, Campus D2 2, 66123 Saarbrücken, Germany; Helmholtz Institute for Pharmaceutical Research Saarland, Helmholtz Center for Infection Research, Campus E8 1, 66123 Saarbrücken, Germany; Center for Biophysics, Saarland University, Campus Saarland, 66123 Saarbrücken, Germany; Max Planck Bristol Centre for Minimal Biology, Cantock's Close, Bristol BS8 1TS, United Kingdom. Electronic address:
Tissue functions rely on complex structural, biochemical, and biomechanical cues that guide cellular behavior and organization. Synthetic cells, a promising new class of biomaterials, hold significant potential for mimicking these tissue properties using simplified, nonliving building blocks. Advanced synthetic cell models have already shown utility in biotechnology and immunology, including applications in cancer targeting and antigen presentation.
View Article and Find Full Text PDFJ Chromatogr B Analyt Technol Biomed Life Sci
January 2025
Universite Claude-Bernard Lyon 1, CNRS, CPE-Lyon, CP2M, UMR 5128, Villeurbanne, France. Electronic address:
Carboxylic acids and aromatic compounds are essential building blocks and starting materials for the production of a wide range of fine chemicals and materials. Their recovery from kraft black liquor, an industrial effluent from pulp and paper mills, is a promising way to produce alternative bio-based chemicals. Reliable methods are needed to identify and quantify the molecules of interest in complex mixtures such as black liquors.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
Laboratory of Construction Materials, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland.
Fired clay bricks (FCBs) are a dominant building material globally due to their low cost and simplicity of production, especially in low- and middle-income countries. With a projected rising housing demand, commensurate growth in brick demand is anticipated, the production of which could result in significant greenhouse gas (GHG) emissions. Robust models are needed to estimate brick demand and emissions to systematically address decarbonization pathways.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!