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Electrochemistry and Electrogenerated Chemiluminescence of 1,3,5-Tri(anthracen-10-yl)-benzene-Centered Starburst Oligofluorenes.

J Am Chem Soc

February 2016

Center for Electrochemistry, Department of Chemistry and Biochemistry, The University of Texas, Austin, Texas 78712, United States.

The electrochemistry and electrogenerated chemiluminescence (ECL) of three 1,3,5-tri(anthracen-10-yl)-benzene-centered starburst oligofluorenes (T1-T3) are reported in this paper. The compounds T1-T3 contain 1,3,5-tri(anthracen-10-yl)-benzene as a core with fluorene as an arm from monofluorene to trifluorene groups (n = 1-3), generating a rigid three-dimensional structure. The electrochemical behaviors of these compounds are likely to be tuned by the fluorene arms.

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