Inhibition of Clostridium botulinum by nitrite was potentiated by the addition of Fe(II) or Fe(III) to the culture medium. The effect of iron was more pronounced when nitrite was added after autoclaving.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC187270PMC
http://dx.doi.org/10.1128/am.30.5.768-770.1975DOI Listing

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