The shear response of molecularly thin liquid films on solid substrates when subjected to an applied air stress has been measured. The response corresponds to viscous friction while the same films sheared between two solid surfaces display static friction. These results show that molecularly thin liquid films partially confined by a single solid surface do not solidify as when confined between two solid surfaces. We are also able to observe several novel properties for liquid films on single solid surfaces not previously observed or expected.
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http://dx.doi.org/10.1103/PhysRevLett.85.3902 | DOI Listing |
Carbohydr Polym
March 2025
Department of Chemical Engineering, Chung-Ang University (CAU), Seoul 06974, Republic of Korea. Electronic address:
We investigate the effects of water-processable celluloses on the charge-transport properties in the conducting polymer composites and their solid-state organic electrochemical transistors (OECTs). Water-soluble methyl cellulose (MC) and water-dispersible cellulose nanofiber (CNF) are blended with poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) in solution and used as a conductive channel. Both cellulose-PEDOT:PSS composites show fibrillar structures in thin films with respective dimensions of cellulose.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
School of Physics and Optoelectronic Engineering, Yangtze University, Jingzhou 434023, China.
Chromophores incorporated into rigid polymer matrices may exhibit novel photophysical properties distinct from those in liquid solutions. In this work, we explored the decay path of the second ππ* state (2ππ*) of riboflavin in poly(vinyl alcohol) (PVA) solutions and films with various acidities. Highly efficient internal conversion from 2ππ* to the lowest ππ* state (1ππ*) induced by slight in-plane motion is demonstrated in all PVA solutions and films, irrespective of environmental acidity and rigidification.
View Article and Find Full Text PDFMater Horiz
January 2025
Soft Matter Lab, Department of Chemical Engineering, Shiv Nadar Institution of Eminence Deemed to be University, Greater Noida, 201314, India.
This study focuses on fabricating photonic crystals (PCs) by surfactant-based particle capture at the gas-liquid interface of evaporating sessile droplets. The captured particles form interfacial films, resulting in ordered monolayer depositions manifesting iridescent structural colors. The particle dynamics behind the ordered arrangement is delineated.
View Article and Find Full Text PDFACS Omega
January 2025
Department of Materials Science and Engineering, Gachon University, 1342, Seongnam-daero, Sujeong-gu, Seongnam-si, Gyeonggi-do 13120, South Korea.
This study investigates the enhancement of polypropylene (PP) composites through the incorporation of exfoliated hexagonal boron nitride (h-BN) nanosheets. The preparation process involved exfoliating h-BN in a liquid phase using a high-pressure homogenizer, followed by the coating of PP pellets with the exfoliated nanosheets using an acoustic mixer. Melt extrusion was then employed to fabricate h-BN-reinforced PP composite films.
View Article and Find Full Text PDFAdv Mater
January 2025
Sustainability Institute, The Ohio State University, Columbus, OH, 43210, USA.
Nature provides many examples of the benefits of nanoscopic surface structures in areas of adhesion and antifouling. Herein, the design, fabrication, and characterization of liquid crystal elastomer (LCE) films are presented with nanowire surface structures that exhibit tunable stimuli-responsive deformations and enhanced adhesion properties. The LCE films are shown to curl toward the side with the nanowires when stimulated by heat or organic solvent vapors.
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