AI Article Synopsis
- New measurements and existing literature were combined to analyze the rotational states of CH(3)OD, focusing on its ground vibrational state.
- The dataset included 564 microwave and millimeter-wave lines, along with 4664 far-infrared lines, and achieved a global fit with a weighted standard deviation of 1.060, indicating accurate measurements.
- Results were compared with isotopomers (like (12)CH(3)OH) revealing strong coupling effects between specific rotational states, emphasizing the complexity of the molecule's behavior.
Article Abstract
New millimeter-wave and microwave measurements for CH(3)OD have been combined with previous literature data and with an extended body of Fourier transform far-infrared observations in a full global analysis of the first two torsional states (v(t) = 0 and 1) of the ground vibrational state. The fitted CH(3)OD data set contained 564 microwave and millimeter-wave lines and 4664 far-infrared lines, representing the most recent available information in the quantum number ranges J
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| http://dx.doi.org/10.1006/jmsp.2000.8201 | DOI Listing |
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