For an Ising antiferromagnet, we analyze exact expressions for the one- and two-point correlation functions for spins on the edge of a square lattice with a magnetic field applied to the surface sites. Two different edge orientations, with respect to the crystal axes, are treated. At bulk criticality, we confirm that the surface universality class depends on the edge orientation and show the importance of having the bulk phase in a pure state. For the two-point function, we find a singularity in the correlation length due to depinning effects which we argue is also present in higher dimensions.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevLett.85.2541 | DOI Listing |
Phys Rev Lett
December 2024
Temple University, Department of Physics, Philadelphia, Pennsylvania 19122, USA.
We have produced state selective molecular angular momentum orientation using dressed states created by a cw optical field. The experiment was carried out with Li_{2} molecules and a combination of left- and right-hand circularly polarized lasers. Our approach exploits the dependence of the Rabi frequency on the quantum number M, which makes it possible to achieve complete M-state selectivity and thus molecular angular momentum orientation relative to laboratory frame space-fixed axes.
View Article and Find Full Text PDFACS Nano
January 2025
Creative Research Initiative Center for Nanospace-confined Chemical Reactions (NCCR), Pohang University of Science and Technology (POSTECH), Pohang 37673, Korea.
Unlike homogeneous metal complexes, achieving absolute control over reaction selectivity in heterogeneous catalysts remains a formidable challenge due to the unguided molecular adsorption/desorption on metal-surface sites. Conventional organic surface modifiers or ligands and rigid inorganic and metal-organic porous shells are not fully effective. Here, we introduce the concept of "ligand-porous shell cooperativity" to desirably reaction selectivity in heterogeneous catalysis.
View Article and Find Full Text PDFCrit Rev Biochem Mol Biol
January 2025
Department of Chemistry, Emory University, Atlanta, GA, USA.
Mononuclear non-heme iron enzymes catalyze a wide array of important oxidative transformations. They are correspondingly diverse in both structure and mechanism. Despite significant evolutionary distance, it is becoming increasingly apparent that these enzymes nonetheless illustrate a compelling case of mechanistic convergence the formation of peroxo species bridging metal and substrate.
View Article and Find Full Text PDFNucleic Acids Res
January 2025
Laboratory of Genome Regeneration, Institute for Quantitative Biosciences, The University of Tokyo, 1-1-1 Yayoi, Bunkyo-ku, Tokyo113-0032, Japan.
Nonlinear emission phenomena observed in transition metal dichalcogenides (TMDCs) have significantly advanced the development of robust nonlinear optical sources within two-dimensional materials. However, the intrinsic emission characteristics of TMDCs are inherently dependent on the specific material, which constrains their tunability for practical applications. In this study, we propose a strategy for the selective enhancement and modification of second-harmonic generation (SHG) emission in a multilayer WS flake through the implementation of a silicon (Si)-based circular Bragg grating (CBG) structure positioned on an Au/SiO substrate.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!