Study Design: A biomechanical study of the rigidity of various scoliosis constructs instrumented with and without caudal pedicle screw anchors and with none, one, or two cross-link devices.
Objectives: To determine whether the increased torsional rigidity provided by distal pedicle screw fixation might make cross-linking unnecessary.
Summary Of Background Data: Pedicle screws and cross-linking devices have been shown to increase the structural rigidity of spinal constructs. Their relative contributions to scoliosis construct rigidity has not been determined.
Methods: "Short" (T2-T11) and "long" (T2-L3) scoliosis constructs were mounted on an industrially fabricated spine model and tested in a hydraulic testing machine. Four different short and four different long constructs were tested: hooks only, hooks with concave side thoracic sublaminar wires, hooks with distal pedicle screw anchors, and hooks, distal pedicle screw anchors, and concave thoracic sublaminar wires. There were four iterations for each construct tested: no cross-links, one superior cross-link at T4-T5, one inferior cross-link at T9-T10, and two cross-links. Torsional rigidity was tested by applying a rotational torque at T2. Vertebral body motion was recorded with a three-dimensional video analysis system.
Results: Constructs with distal pedicle screws were statistically more rigid in torsion than those with hooks as distal anchors. The additional torsional rigidity from one or more cross-links was negligible compared with that provided by pedicle screws.
Conclusions: With pedicle screws as distal anchors in scoliosis constructs, cross-linking with one or two devices adds very little additional rotational stiffness and may be unnecessary in many cases.
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http://dx.doi.org/10.1097/00007632-200008010-00006 | DOI Listing |
Adv Sci (Weinh)
January 2025
Guangdong-Hong Kong Joint Laboratory for Carbon Neutrality, Jiangmen Laboratory of Carbon Science and Technology, Jiangmen, Guangdong, 529199, P. R. China.
Giant dimeric acceptors (GDAs), a sub-type of acceptor materials for organic solar cells (OSCs), have garnered much attention due to the synergistic advantages of their monomeric and polymeric acceptors, forming a well-defined molecular structure with a giant molecular weight for high efficiency and stability. In this study, for the first time, two new GDAs, DYF-V and DY2F-V are designed and synthesized for OSC operation, by connecting one vinylene linker with the mono-/di-fluorinated end group on two Y-series monomers, respectively. After fluorination, both DYF-V and DY2F-V exhibit bathochromic absorption and denser packing modes due to the stronger intramolecular charge transfer effect and torsion-free backbones.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States.
The unique reactivity of molecules under force commands an understanding of structure-mechanochemical activity relationships. While conceptual frameworks for understanding force transduction in many systems are established, systematic investigations into force-coupled molecular torsions are limited. Here, we describe a novel fluorenyl naphthopyran mechanophore for which mechanical force is uniquely coupled to the torsional motions associated with the overall chemical transformation as a result of the conformational rigidity imposed by the fluorene group.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Department of Chemistry, New York University, New York, New York 10003, USA.
The water trimer, as the smallest water cluster in which the three-body interactions can manifest, is arguably the most important hydrogen-bonded trimer. Accurate, fully coupled quantum treatment of its excited intermolecular vibrations has long been an elusive goal. Here, we present the methodology that for the first time allows rigorous twelve-dimensional (12D) quantum calculation of the intermolecular vibration-tunneling eigenstates of the water trimer, with the monomers treated as rigid.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Faculty of Civil and Environmental Engineering, West Pomeranian University of Technology in Szczecin, Al. Piastów 17, 70-310 Szczecin, Poland.
Dynamic analysis of structures is a key challenge in structural engineering, especially in choosing effective and accurate numerical methods. Steel-concrete composite structures, commonly used in bridges and floors, require calculations of dynamic parameters to ensure safety and comfort. Few studies compare the effectiveness of the finite element method (FEM) and the rigid finite element method (RFEM) in the dynamic analysis of such structures.
View Article and Find Full Text PDFJ Biomech
January 2025
Department of Mechanical Engineering & Mechanics, Lehigh University, 27 Memorial Drive West, Bethlehem, PA 18015, USA. Electronic address:
In large animal models of bone fracture repair, postmortem torsional testing is commonly used to assess healing biomechanics. Bending and axial tests are physiologically relevant, but much less commonly performed. Virtual torsional testing using image-based finite element models has been validated to postmortem bench tests, but its predictive value for capturing whole-bone mechanics and fracture healing quality under other physiologically relevant loading modes has not yet been established.
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