Statement Of Problem: The ringless casting procedure is in use in clinical dentistry, although there is no adequate scientific data to support its use.
Purpose: This study compared the vertical margin accuracy of lost wax castings produced with the conventional casting technique using a metal ring and a technique that uses a ringless system.
Material And Methods: From copings fabricated on a metal die, 30 castings were produced from a high palladium alloy for metal ceramic restorations (Argedent). Ten castings were cast with Bellavest T (Bego) phosphate-bonded investment with the ringless technique, 10 were cast with the same investment with a metal ring, and the final 10 were cast using Hi-temp (Whip Mix) phosphate-bonded investment with a metal ring. The internal surface of the castings were not modified before seating with finger pressure. For vertical margin discrepancy measurements, an optical microscope at a magnification of 100x was used. Data were analyzed with 1-way multivariate ANOVA (repeated measures) and the Student-Newman-Keuls test.
Results: When following the manufacturers' recommendations, the castings of the ringless technique provided less vertical margin discrepancy (mean value 181 +/- 71 microm) than the castings produced with the conventional metal ring technique (290 +/- 87 microm and 291 +/- 88 microm). The difference was significant (P <. 001).
Conclusion: The ringless technique may produce accurate castings for use in fixed prosthodontics, therefore further investigation is needed to develop a protocol for its use.
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http://dx.doi.org/10.1067/mpr.2000.107783 | DOI Listing |
Phys Chem Chem Phys
January 2025
School of Physics and Optoelectronic Engineering, Yangtze University, Jingzhou, 434023, P.R. China.
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View Article and Find Full Text PDFOrg Lett
January 2025
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong 273165, China.
The enantioselective ring-opening reactions of methylenecyclopropanes (MCPs) involving C-C bond activation via oxidative addition of transition metals have been rarely reported. Here, we disclose a Pd/Cu-catalyzed enantio- and regioselective coupling between cyclic imino esters and MCPs to produce α-allylated 2-pyrrole derivatives. In this reaction, azomethine ylide formed by a chiral copper catalyst with ketimine ester would serve as a nucleophile to react with activated MCPs via palladium catalysis.
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January 2025
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, PR China. Electronic address:
Modern microelectronics industries urgently require dielectric materials with low thermal expansion coefficients, low dielectric constants, and minimal dielectric loss. However, the design principles of materials with low dielectric constants and low thermal expansion are contradictory. In this study, a new diamine monomer containing a dibenzocyclooctadiene unit (DBCOD-NH) was designed and synthesized, which was subsequently polymerized with high fluorine content 4,4'-hexafluoroisopr-opylidene diphthalic anhydride and 4,4'-diamino-2,2'-bis(trifleoromethyl)biphenyl to obtain a series of fluorinated polyimides (PIs).
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India.
Hydrogen production via water-splitting or ammonia electrolysis using transition metal-based electrodes is one of the most cost-effective approaches. Herein, ca. 1-4% of Pt atoms are stuffed into a wolframite-type NiWO lattice to improve the electrocatalytic efficiency.
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