Objective: We report on radioactive contamination of packing materials from a 133Xe shipment.
Methods: A 2-vial 133Xe shipment was monitored using a survey meter before opening. Both vials were immediately assayed in a dose calibrator. The packing materials were monitored and contamination was detected.
Results: The maximum surface reading of the shipment was 7.0 microSv/h. This was higher than previous shipments (1.1 +/- 0.3 microSv/h). One vial was 544 MBq while the other vial was only 474 MBq. Previous shipments were 565 +/- 13 MBq/vial. Monitoring and imaging revealed 133Xe contamination within the packing materials. Xenon-133 escaped from the packing materials over time. The lower activity vial continued to leak 133Xe over time.
Conclusion: Careful monitoring of 133Xe shipments before and after opening along with assaying vials on receipt can indicate vial leakage and radioactive contamination so steps can be taken to minimize radiation exposure to the staff.
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The elimination of the A' unit from -type Y6-derivatives has led to the development of a new class of -benzodipyrrole (-BDP)-based A-DBD-A-type NFAs. In this work, two new A-DBD-A-type NFAs, denoted as CFB and CMB, are designed and synthesized, where electron-withdrawing fluorine atoms and electron-donating methyl groups are substituted on the benzene ring of the -BDP moiety, respectively. CFB exhibits a blue-shifted absorption spectrum, stronger intermolecular interactions, shorter π-π stacking distances, and more ordered 3D intermolecular packing in the neat and blend films, enabling it to effectively suppress charge recombination in the PM6:CFB device showing a higher PCE of 16.
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January 2025
Packing and Packaging Materials Department, Institute of Chemical Industries Research, National Research Centre 33 El Behooth St., Dokki Giza Egypt +20 2 33371718.
Nanofiltration (NF) separation technology is a low-pressure filtration process, which is highly efficient and environmentally friendly. As a result, it has found wide application in water treatment. This work describes the preparation of flat sheet membranes the phase inversion method using blends of hyperbranched polyester amide (PEA) and polyether sulphone (PES) in definite ratios.
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Department of Gaseous Electronics (F6), Jožef Stefan Institute, Jamova cesta 39, 1000 Ljubljana, Slovenia.
The production, conversion and storage of energy based on electrocatalysis, mainly assisted by oxygen evolution reaction (OER), plays a crucial role in alkaline water electrolyzers (AWEs) and fuel cells. Nevertheless, the insufficient availability of highly efficient catalyst materials at a reasonable cost that overcome the sluggish electrochemical kinetics of the OER is one of the significant obstacles. Herein, we report a fast and facile synthesis of vapor phase deposition of dual-phase nickel sulfide (Ni-sulfide) using low-temperature annealing in the presence of HS and demonstrated as an efficient catalyst for OER to address the issues with sluggish electrochemical kinetics.
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Department of Industrial Engineering, University of Padova, Via Marzolo 9, 35131 Padova, Italy. Electronic address:
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View Article and Find Full Text PDFOrg Lett
January 2025
Department of Materials Science, State Key Laboratory of Molecular Engineering of Polymers, Laboratory of Molecular Materials and Devices, Fudan University, Shanghai 200433, China.
Two series of polycyclic aromatic hydrocarbon isomers ( and , and and ) were designed and synthesized by isomerically fusing phenanthrene with thiophene and thieno[3,2-]thiophene, respectively. All of the new target molecules were confirmed by single-crystal X-ray analysis, and it was found that the solid-state packing can be effectively modulated through a combination of π-extended and isomeric fused strategies. Meanwhile, compared with thiophene ring-terminated isomers and , both having a V-shaped geometry and showing no obvious self-assembly behavior, π-extended unit thieno[3,2-]thiophene-terminated isomer displays a V-shaped structure with moderate self-assembly properties and isomer exhibits a C-shaped configuration with further enhanced self-assembly properties.
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