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Seasonal trends and sources of dicarboxylic acids in fine aerosol over the Brahmaputra valley, North-East India.
Environ Sci Pollut Res Int
January 2025
Department of Civil Engineering, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh, 208016, India.
The atmospheric dicarboxylic acids (DCAs) have a significant impact on the climate and indirectly affect human health, making them important organic substances. PM bound DCAs were analysed for Jorhat, India, 2019. In addition to the temporal variability, seasonal variation throughout the year and the impact of varying meteorological factors on DCAs concentration have also been studied.
View Article and Find Full Text PDFBoosting the oxygen reduction activity on metal surfaces by fine-tuning interfacial water with midinfrared stimulation.
Innovation (Camb)
January 2025
International Joint Laboratory of Catalytic Chemistry, College of Sciences, Shanghai University, Shanghai 200444, China.
Heterogeneous catalysis at the metal surface generally involves the transport of molecules through the interfacial water layer to access the surface, which is a rate-determining step at the nanoscale. In this study, taking the oxygen reduction reaction on a metal electrode in aqueous solution as an example, using accurate molecular dynamic simulations, we propose a novel long-range regulation strategy in which midinfrared stimulation (MIRS) with a frequency of approximately 1,000 cm is applied to nonthermally induce the structural transition of interfacial water from an ordered to disordered state, facilitating the access of oxygen molecules to metal surfaces at room temperature and increasing the oxygen reduction activity 50-fold. Impressively, the theoretical prediction is confirmed by the experimental observation of a significant discharge voltage increase in zinc-air batteries under MIRS.
View Article and Find Full Text PDFBoosting the Reaction Rate of Blocky Aluminum-Water via Ultrasound-Based Surface Engineering in Room-Temperature Liquid Metal Solvent.
Langmuir
January 2025
Laboratory of Advanced Light Alloy Materials and Devices, Yantai Nanshan University, Longkou 265713, China.
Hydrogen gas holds immense promise as a clean fuel source, yet its widespread adoption faces significant challenges in storage and transportation due to its gaseous and highly flammable nature. An increasingly attractive approach to overcoming these limitations involves reacting aluminum (Al) blocks with water to produce hydrogen, providing an alternative distribution mechanism in which Al blocks can be used as "hydrogen storage" for on-demand production at any location. However, current methods suffer poor hydrogen production rates and yields, primarily influenced by the limited contact area between Al and the catalyst, such as Ga-based room-temperature liquid metal.
View Article and Find Full Text PDFStructural Basis of Ultralow Capacitances at Metal-Nonaqueous Solution Interfaces.
J Am Chem Soc
January 2025
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China.
Metal-nonaqueous solution interfaces, a key to many electrochemical technologies, including lithium metal batteries, are much less understood than their aqueous counterparts. Herein, on several metal-nonaqueous solution interfaces, we observe capacitances that are 2 orders of magnitude lower than the usual double-layer capacitance. Combining electrochemical impedance spectroscopy, atomic force microscopy, and physical modeling, we ascribe the ultralow capacitance to an interfacial layer of 10-100 nm above the metal surface.
View Article and Find Full Text PDFOptimized Interface Engineering Enhances Carrier and Phonon Scattering for Superior Thermoelectric Performance in Yb-Filled Skutterudites.
ACS Appl Mater Interfaces
January 2025
Key Laboratory of Radiation Physics and Technology, Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, Chengdu 610064, China.
Thermoelectric (TE) performance in materials is often constrained by the strong coupling between carrier and phonon transport, necessitating trade-offs between electrical and thermal properties that limit improvements in the figure of merit (). Herein, a novel strategy is proposed to achieve simultaneous energy filtering and enhanced phonon scattering, effectively optimizing the TE properties of CoSb-based skutterudites. By introducing CuTe nanoprecipitates into the YbCoSb matrix, interfacial barriers are formed, which selectively filter low-energy charge carriers, significantly improving the Seebeck coefficient while maintaining high carrier mobility.
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