A model for red azo pigment Ca4B was characterized structurally using synchrotron radiation. This highly anisotropic ladder structure represents a new structural class in azo pigment chemistry. The picture shows that the calcium atoms coordinate in a complex manner to three azo ligands (one terdentate, one bidentate, and one monodentate) and two water molecules simultaneously.

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http://dx.doi.org/10.1002/(sici)1521-3773(20000204)39:3<638::aid-anie638>3.0.co;2-kDOI Listing

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