AI Article Synopsis
- An MP2 study showed that a water molecule forms a hydrogen bond with trans-[Pt(OH)(2)(NH(3))(2)], characterized by a HO-H⋅⋅⋅Pt(II) interaction.
- This hydrogen bond has a significant dispersion component of about 4 kcal/mol.
- The dispersion interaction is consistent regardless of the charge on the platinum complex, indicating it is common in aqueous solutions of Pt(II) complexes.
Article Abstract
An MP2 ab initio study of the interaction between a H(2)O molecule and trans-[Pt(OH)(2)(NH(3))(2)] revealed a HO-H small middle dot small middle dot small middle dotPt(II) hydrogen bond (see picture) with a strong dispersion component (ca. 4 kcal mol(-1)). This dispersion interaction is independent of the charge on the complex and is likely to be ubiquitous in aqueous solutions of Pt(II) complexes.
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| http://dx.doi.org/10.1002/(sici)1521-3773(20000103)39:1<198::aid-anie198>3.0.co;2-o | DOI Listing |
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