We retrospectively analyzed CT scans from 23 patients with non-traumatic colorectal perforation. We compared the sensitivity of CT and plain film radiography in the detection of free gas. Free gas was observed in 7 of the 23 cases (30.4%) on plain film radiography and 16 of the 23 cases (69.6%) on CT. Retroperitoneal abscess was demonstrated in 6 of the 7 patients without free gas on CT. Extraluminal air and abscess covered by the omentum and mesenterium were demonstrated in the remaining one patient. The site of perforation was identified in 19 of the 23 patients (82.6%) on CT. CT was useful for demonstrating retroperitoneal free gas, changes in mesenteric fat, extraluminal feces, and tumors. We conclude that CT is indicated in cases of suspected colorectal perforation.
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Chempluschem
January 2025
L V Pisarzhevskii Institute of Physical Chemistry NAS of Ukraine: Institut fiziceskoj himii imeni L V Pisarzevskogo Nacional'na akademia nauk Ukraini, Department of free radicals, UKRAINE.
This study unveils a novel property of polyaniline by establishing its catalytic activity in heterogeneous hydrogenation with molecular hydrogen. Polyaniline was activated by heat-treating at different temperatures in a hydrogen atmosphere. The sample treated at 300 °C exhibited the highest catalytic activity for ethylene hydrogenation in the gas phase at atmospheric pressure and for p-nitrotoluene or α-methylstyrene hydrogenation in the liquid phase.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
Chemical & Material Sciences Division, CSIR-Indian Institute of Petroleum, Haridwar Road, Mohkampur, Dehradun-248005, India.
Retraction of 'CO as oxidant: an unusual light-assisted catalyst free oxidation of aldehydes to acids under mild conditions' by Shafiur Rehman Khan , , 2022, , 2208-2211, https://doi.org/10.1039/D1CC06057K.
View Article and Find Full Text PDFNat Commun
January 2025
Laboratory of Environment-Enhancing Energy (E2E), College of Water Resources and Civil Engineering, China Agricultural University, Beijing, 100083, China.
Biocrude derived from biomass via hydrothermal liquefaction (HTL) is a sustainable substitute for petroleum to obtain energy and biochemicals. Upgrading biocrude inevitably faces the trade-off between consuming large amounts of hydrogen via hydrotreating and high yield of solid residue without additional hydrogen. In this work, we report a non-hydrogenated refinery paradigm for nearly complete valorization (~90%), via co-generating green coal and bio-lubricant.
View Article and Find Full Text PDFDalton Trans
January 2025
Department of Chemistry, Jadavpur University, Jadavpur, Kolkata-700 032, West Bengal, India.
This study presents the synthesis of a Cd(II) based hydrophobic three dimensional crystalline network material (CNM), [Cd(L)(LH)(bpe)], {L = {4,4'-(hexafluroisopropylidine)bis(benzoate)} and 1,2-di(4-pyridyl) ethylene (bpe)}, 1(Cd), by employing the slow-diffusion method. The three-dimensional structure of 1(Cd) was determined by single crystal X-ray diffraction and characterized by powder X-ray diffraction (PXRD), FT-IR spectroscopy and thermogravimetric analysis (TGA). Subsequently, post-synthetic modification of 1(Cd) with Cu(II) at room temperature led to the formation of isostructural 1(Cu) with partial substitution.
View Article and Find Full Text PDFAppl Environ Microbiol
January 2025
Clinical Infection Department, Chelsea and Westminster Hospital NHS Foundation Trust, London, United Kingdom.
Unlabelled: Remote polar regions offer unique opportunities and significant challenges for antimicrobial resistance research in a near-pristine environment. While core microbiology techniques continue to have an important role in supporting environmental research, the severe cold climate presents considerable challenges to laboratory research. We explore adaptations required for core bacteriology investigations in polar regions on an unsupported remote expedition c.
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