Stable carbon and oxygen isotope values from soil carbonates were used to determine the vegetation context of archaeological sites and local climatic conditions represented in a approximately 0.99 Ma paleosol that is exposed laterally in the Olorgesailie basin, southern Kenya rift valley. As part of this landscape-scale project, samples of an upper Member 1 paleosol were analyzed along nearly 4 km of outcrop in three adjacent parts of the basin. Modern East African soil and plant community analogs are used to interpret the isotope ratios. The carbon isotopic composition of the paleosol carbonates indicates that the area supported a local biomass of about 75-100% C(4)plants during the period of soil formation. After averaging the data for each trench, an open C(4)grassland is represented by half of the carbon values, with wooded grassland more abundant across the paleolandscape than it is in the area now. This vegetational reconstruction is supported by the mammalian faunal assemblage, which has a high percentage of grazers. Although the relatively small sample size outside the main excavation area precludes firm characterization of vegetational diversity across the basin in upper Member 1 times, eastern and western localities in the study area may have had more woody C(3)plants than the widely sampled zone in between. Oxygen isotopes indicate that the lowland basin was slightly cooler and moister than today's semi-arid climate, with greater annual rainfall. Archaeological traces have a virtually continuous distribution across the paleolandscape, but vary in density of occurrence. With the strong evidence for C(4)grassland as the primary vegetation context across most of the study area, no habitat preference by the Acheulean toolmakers at Olorgesailie is shown in our initial comparison between carbon isotope values and stone/bone densities.
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http://dx.doi.org/10.1006/jhev.1999.0343 | DOI Listing |
Sci Total Environ
January 2025
US Geological Survey, New England Water Science Center, Northborough, MA, USA.
Groundwater-dependent ecosystems in areas with industrial land use are at risk of exposure to a PFAS chemicals. We investigated one such system with several known PFAS source areas, where high and low permeability sediments (glacial) coupled with groundwater-lake and groundwater/surface-water interactions created complex 'source to seep' dynamics. Using heat-tracing and chemical methods, numerous preferential groundwater discharge zones were identified and sampled across the upper Quashnet River stream-wetland system in Mashpee, MA, USA, downgradient of Joint Base Cape Cod (JBCC).
View Article and Find Full Text PDFPharmaceutics
January 2025
Department of Materials Science, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennoudai 1-1-1, Tsukuba 305-8573, Ibaraki, Japan.
Orally administered sorafenib has shown limited improvement in overall survival for non-small-cell lung cancer patients, likely due to poor pharmacokinetics and adverse effects, including gastrointestinal toxicity. To address these issues, we developed silica-containing antioxidant nanoparticles (siRNP) as a carrier to enhance the therapeutic efficacy of lipophilic sorafenib. Sorafenib was loaded into siRNP via dialysis (sora@siRNP).
View Article and Find Full Text PDFBiology (Basel)
December 2024
Andean Geothermal Center of Excellence, University of Chile, Santiago 8370446, Chile.
We used otolith chemistry to test and complement current hypotheses regarding habitat use and connectivity between sub-populations in Area 48 of the Commission for the Conservation of Antarctic Marine Living Resources (CCAMLR). Sagittal otoliths from 45 fish sampled near the South Orkney Islands were analysed. Their elemental (Li, Na, Mg, Cr, Mn, Sr, Sn, and Ba relative to Ca) and isotopic (δO and δC) signatures were examined in both the nuclear and marginal regions, representing juvenile and adult stages.
View Article and Find Full Text PDFSci Rep
January 2025
The Rowett Institute, University of Aberdeen, Foresterhill, Aberdeen, UK.
Vitamin D is essential for healthy skeletal growth and is increasingly recognised for its role in chronic disease development, inflammation and immunity. 25-hydroxyvitamin D (25(OH)D) concentrations are an indicator of vitamin D status and are normally analysed in plasma or serum samples in clinical settings, while archaeological studies rely on the identification of skeletal markers of vitamin D deficiency, such as rickets. Here, we determined 25(OH)D concentrations in hair specimens ('locks') that had been sampled close to the root, aligned by cut end, and sliced into sequential segments from participants (n = 16), from Aberdeen, Scotland, using a modified protocol designed to minimise sample size.
View Article and Find Full Text PDFSci Adv
January 2025
Institute of Energy, School of Earth and Space Sciences, Peking University, Beijing 100871, China.
The origins of natural hydrogen in natural gas systems of sedimentary basins and the capacity of these systems to store hydrogen remain inadequately understood, posing crucial questions for the large-scale exploration of natural hydrogen. This study reports on the natural gas composition, stable carbon and hydrogen isotopic values, and helium isotopic values of gas samples collected from the Qingshen gas deposit within volcanic rocks of the Songliao Basin. Natural hydrogen primarily originates from water radiolysis, water-rock interactions (WRI), and mantle.
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