Cultures able to dechlorinate cis-1,2-dichloroethene (cDCE) were selected with ethene (3-20%, v/v) as the sole source of carbon and energy. One mixed culture (K20) could degrade cDCE (400 &mgr;mol l(-1)) or vinyl chloride (100 &mgr;mol l(-1)) in the presence of ethene (= 80 &mgr;mol l(-1) and = 210 &mgr;mol l(-1), respectively). This culture consists of at least five bacterial strains. All five strains were able to degrade cDCE cometabolically in pure culture. The mixed culture K20 was highly tolerant against cDCE (up to 6 mmol l(-1) in the liquid phase). Degradation of cDCE (200 &mgr;mol l(-1)) was not affected by the presence of trichloroethene (100 &mgr;mol l(-1)) or tetrachloroethene (100 &mgr;mol l(-1)). Transformation yields (T(y), defined as unit mass of chloroethene degraded per unit mass of ethene consumed) of the mixed culture K20 were relatively high (0.51 and 0.61 for cDCE and vinyl chloride, respectively). The yield for cDCE with ethene as auxiliary substrate was ninefold higher than any values reported with methane or methane/formate as auxiliary substrate. The viability of the cells of the mixed culture K20 (0.3 mg of cells ml(-1)) was unaffected by the transformation of = 200 &mgr;mol l(-1) cDCE in 300 min.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1007/s002030050766 | DOI Listing |
J Environ Manage
January 2025
Jerzy Haber Institute of Catalysis and Surface Chemistry Polish Academy of Sciences, Niezapominajek 8, 30-239, Kraków, Poland.
To clean or not to clean? The solution to this dilemma is related to understanding the plasticiser migration which has a few practical implications for the state of museum artefacts made of plasticised poly(vinyl chloride) - PVC and objects stored in their vicinity. The consequences of this process encompass aesthetic changes due to the presence of exudates and dust deposition, an increase in air pollution and the development of mechanical stresses. Therefore, this paper discusses the plasticiser migration in PVC to provide evidence and support the development of recommendations and guidelines for conservators, collection managers and heritage scientists.
View Article and Find Full Text PDFAnal Chem
January 2025
Department of Chemistry, University of Waterloo, 200 University Avenue W., Waterloo, Ontario N2L 3G1, Canada.
Research has shown microplastic particles to be pervasive pollutants in the natural environment, but labor-intensive sample preparation, data acquisition, and analysis protocols continue to be necessary to navigate their diverse chemistry. Machine learning (ML) classification models have shown promise for identifying microplastics from their Raman spectra, but all attempts to date have focused on the lower energy "fingerprint" region of the spectrum. We explore strategies to improve ML classification models based on the -nearest-neighbor algorithm by including other regions of the Raman spectra.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Chemistry, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal 576104, Karnataka, India.
The potential of advanced energy storage devices lies in using solid biodegradable polymer electrolytes. This study is focused on a solid blend polymer electrolyte (SBPE) film based on chitosan (CS)-poly(vinyl alcohol) (PVA) blend matrix doped with magnesium chloride (MgCl) salt via solution casting. The interaction of MgCl was verified via X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy.
View Article and Find Full Text PDFThe objective of the study was to examine the mechanical and electrostatic properties of poly(vinyl chloride) intended for use in protective footwear. The poly(vinyl chloride) material was made with graphite (flake side dimensions 5 and 10 µm) additive in weight concentration variants from 0.5 to 10.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.
Poly(vinyl chloride) (PVC) and polystyrene (PS) are among the least recycled plastics. In this work, we developed a simple and novel strategy to valorize PVC and PS plastics via photothermal conversion to (1-chloroethyl)benzene, a commodity chemical with excellent versatility. As PVC is known to release HCl gas and decompose into conjugated polyenes, we envisioned a dual role for PVC plastics.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!