The addition of elemental selenium to organolithium compounds 1 or organic selenates 2 gives organic diselenolates 3. The reactions proceed by the insertion of two selenium atoms into the carbon-metal bonds or of one selenium atom into a selenolate. Evidence for the existence of n-butyldisilenol has also been obtained.
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| http://dx.doi.org/10.1002/(sici)1521-3773(19990802)38:15<2245::aid-anie2245>3.0.co;2-j | DOI Listing |
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