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Low-threshold anisotropic polychromatic emission from monodisperse quantum dots.
Natl Sci Rev
February 2025
Institute of Nanoscience and Applications, Department of Electrical and Electronic Engineering, Southern University of Science and Technology, Shenzhen 518055, China.
Colloidal quantum dots (QDs) are solution-processable semiconductor nanocrystals with favorable optoelectronic characteristics, one of which is their multi-excitonic behavior that enables broadband polychromatic light generation and amplification from monodisperse QDs. However, the practicality of this has been limited by the difficulty in achieving spatial separation and patterning of different colors as well as the high pumping intensity required to excite the multi-excitonic states. Here, we have addressed these issues by integrating monodisperse QDs in multi-excitonic states into a specially designed cavity, in which the QDs exhibit an anisotropic polychromatic emission (APE) characteristic that allows for tuning the emission from green to red by shifting the observation direction from perpendicular to lateral.
View Article and Find Full Text PDFHot-Exciton Mechanism with Diphenyl Anthracene Core Unit: A Detailed Theoretical Study.
Chem Asian J
January 2025
Department of Chemistry, Birla Institute of Technology and Science (BITS) Pilani, Hyderabad Campus, Hyderabad, 500078, India.
Hot-exciton materials, among all kinds of organic light-emitting diode (OLED) emitters, have better exciton utilization efficiency and efficiency roll-off, making them possible for their practical applications. We studied the photophysical properties of a few hot-exciton molecules based on an anthracene core unit to efficiently harvest all triplet excitons to the lowest excited singlet state. The conversion of triplet exciton to singlet exciton utilizing hRISC can be enhanced due to the ππ*←nπ* transition channel.
View Article and Find Full Text PDFHow Structure and Hydrostatic Pressure Impact Excited-State Properties of Organic Room-Temperature Phosphorescence Molecules: A Theoretical Perspective.
J Phys Chem A
January 2025
Shandong Province Key Laboratory of Medical Physics and Image Processing Technology, School of Physics and Electronics, Shandong Normal University, Jinan 250014, China.
Organic room-temperature phosphorescence (RTP) emitters with long lifetimes, high exciton utilizations, and tunable emission properties show promising applications in organic light-emitting diodes (OLEDs) and biomedical fields. Their excited-state properties are highly related to single molecular structure, aggregation morphology, and external stimulus (such as hydrostatic pressure effect). To gain a deeper understanding and effectively regulate the key factors of luminescent efficiency and lifetime for RTP emitters, we employ the thermal vibration correlation function (TVCF) theory coupled with quantum mechanics/molecular mechanics (QM/MM) calculations to investigate the photophysical properties of three reported RTP crystals (Bp-OEt, Xan-OEt, and Xan-OMe) with elastic/plastic deformation.
View Article and Find Full Text PDFPhoton Upconversion of Defect-Bound Excitons in hBN-Encapsulated MoS Monolayer.
J Phys Chem C Nanomater Interfaces
November 2024
Department of Experimental Physics, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland.
Atomic defects associated with vacancies in two-dimensional transition metal dichalcogenide monolayers efficiently trap charged carriers and strongly localize excitons. Defects in semiconducting monolayers are seldomly utilized for enhancing optical phenomena, although they may provide resonant intermediate states within the energy band gap for applications with multiphoton excitations, like highly efficient and thermally robust photon upconversion. In an MoS monolayer encapsulated by hBN with high defect and resident electron densities, we observe an upconversion of localized exciton (X) emission with a huge energy gain of up to 290 meV.
View Article and Find Full Text PDFBright dipolar excitons in twisted black phosphorus homostructures.
Science
November 2024
State Key Laboratory of Surface Physics, Key Laboratory of Micro- and Nano-Photonic Structures (Ministry of Education), Shanghai Key Laboratory of Metasurfaces for Light Manipulation, and Department of Physics, Fudan University, Shanghai 200433, China.
Bright dipolar excitons, which contain electrical dipoles and have high oscillator strength, are an ideal platform for studying correlated quantum phenomena. They usually rely on carrier tunneling between two quantum wells or two layers to hybridize with nondipolar excitons to gain oscillator strength. In this work, we uncovered a new type of bright infrared dipolar exciton by stacking 90°-twisted black phosphorus (BP) structures.
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