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Unified description of thermal and nonthermal laser-induced ultrafast structural changes in materials.

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The ultrafast ionic dynamics in solids induced by intense femtosecond laser excitation are controlled by two fundamentally different yet interrelated phenomena. First, the substantial generation of hot electron-hole pairs by the laser pulse modifies the interatomic bonding strength and characteristics, inducing nonthermal ionic motion. Second, incoherent electron-ion collisions facilitate thermal equilibration between electrons and ions, achieving a uniform temperature on a picosecond timescale.

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