Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1103/PhysRevLett.64.677 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
A Comparison of the Electronic Properties of Selected Antioxidants Vitamin C, Uric Acid, NAC and Melatonin with Guanosine Derivatives: A Theoretical Study.
Molecules
December 2024
DNA Damage Laboratory of the Food Science Department, Faculty of Pharmacy, Medical University of Lodz, ul. Muszynskiego 1, 90-151 Lodz, Poland.
Each cell in the human body is continually exposed to harmful external and internal factors. During evolution, cells have developed various defence systems, divided into enzymatic and non-enzymatic types, to which low-weight molecule antioxidants belong. In this article, the ionisation potential and electron affinity, as well as global reactivity descriptors of Vitamin C, Melatonin, Uric Acids, and N-acetyl-L-cysteine, were theoretically investigated at the MP-2/aug-cc-pVTZ level of theory in the condensed (aqueous) phase.
View Article and Find Full Text PDFFormation of molecularly imprinted polymers: Strategies applied for the removal of protein template (review).
Adv Colloid Interface Sci
December 2024
Department of Physical Chemistry, Institute of Chemistry, Faculty of Chemistry and Geosciences, Vilnius University (VU), Naugarduko Str. 24, LT-03225 Vilnius, Lithuania; Department of Nanotechnology, State Research Institute Center for Physical Sciences and Technology (FTMC), Saulėtekio Ave. 3, LT-10257 Vilnius, Lithuania. Electronic address:
The key step in the entire molecularly imprinted polymer (MIP) preparation process is the formation of the complementary cavities in the polymer matrix through the template removal process. The template is removed using chemical treatments, leaving behind selective binding sites for target molecules within the polymer matrix. Other MIP preparation steps include mixing monomers and template molecules in the appropriate solvent(s), monomer-template complex equilibration, and polymerisation of the monomers around the template.
View Article and Find Full Text PDFThe physiological landscape and specificity of antibody repertoires are consolidated by multiple immunizations.
Elife
December 2024
Department of Biosystems Science and Engineering, ETH Zürich, Basel, Switzerland.
Diverse antibody repertoires spanning multiple lymphoid organs (i.e., bone marrow, spleen, lymph nodes) form the foundation of protective humoral immunity.
View Article and Find Full Text PDFWater Sorption Properties and Hydrothermal Stability of Al-Containing Metal-Organic Frameworks CAU-10 and MIL-96 Studied Using Quasi-Equilibrated Thermodesorption.
Molecules
November 2024
Faculty of Chemistry, Jagiellonian University in Kraków, Gronostajowa 2, 30-387 Kraków, Poland.
A novel experimental technique, quasi-equilibrated temperature-programmed desorption and adsorption (QE-TPDA), was used to study the water sorption properties and hydrothermal stability of aluminum trimesate MIL-96 and aluminum isophthalate CAU-10, which have been selected due to their remarkable sorption properties. The QE-TPDA profiles of water observed for MIL-96 and CAU-10 confirmed the hydrophilic nature of these materials. Complex QE-TPDA profiles indicate that water sorption in MIL-96 follows a three-step pore filling mechanism.
View Article and Find Full Text PDFCorrelation between photolysis quantum yields and efficiency of hydroxyl radicals generation upon excitation of natural iron(III) carboxylates.
Chemosphere
December 2024
V.V. Voevodsky Institute of Chemical Kinetics and Combustion SB RAS, 3 Institutskaya str., 630090, Novosibirsk, Russian Federation. Electronic address:
Article Synopsis
- Fe(III) complexes with carboxylic acids are crucial for environmental photochemistry and could be effective in advanced oxidation processes (AOPs).
- The study presents two methods to accurately determine quantum yields for photolysis and hydroxyl (OH) radical generation from these complexes when exposed to UV light.
- New findings establish a correlation between the quantum yields of OH generation for various Fe complexes and resolve discrepancies in previous literature, enhancing the understanding of their efficiency in environmental applications.
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!