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Binding the Power of Cycloaddition and Cross-Coupling in a Single Mechanism: An Unexpected Bending Journey to Radical Chemistry of Butadiynyl with Conjugated Dienes.
J Phys Chem Lett
January 2025
Department of Chemistry, University of Hawai'i at Ma̅noa, Honolulu, Hawaii 96822, United States.
What if an experiment could combine the power of cycloaddition and cross-coupling with the formation of an aromatic molecule in a single collision? Crossed molecular beam experiments augmented with electronic structure and statistical calculations provided compelling evidence on a novel radical route involving 1,3-butadiynyl (HCCCC; X∑) radicals synthesizing (substituted) arylacetylenes in the gas phase upon reactions with 1,3-butadiene (CHCHCHCH; XA) and 2-methyl-1,3-butadiene (isoprene; CHC(CH)CHCH; XA'). This elegant mechanism merges two previously disconnected concepts of cross-coupling and cycloaddition-aromatization in a single collision event via the formation of two new C(sp)-C(sp) bonds and bending the 180° moiety of the linear 1,3-butadiynyl radical out of the ordinary by 60° to 120°. In addition to its importance to fundamental organic chemistry, this unconventional mechanism links two previously separated routes of gas-phase molecular mass growth processes of polyacetylenes and polycyclic aromatic hydrocarbons (PAHs), respectively, in low-temperature environments such as in cold molecular clouds like the Taurus Molecular Cloud (TMC-1) and in hydrocarbon-rich atmospheres of planets and their moons such as Titan, which revises the established understanding of low-temperature molecular mass growth processes in the Universe.
View Article and Find Full Text PDFMulti-indices approach for comprehensive appraisal of groundwater quality and the implication on human health in the Amaravathi basin, Southern India.
Environ Monit Assess
January 2025
Department of Water Resource and Ecosystems, IHE Delft Institute for Water Education, Westvest 7, Delft, NH, Netherlands.
Groundwater is often used directly by the public in several river basins of India. Hence, this study was carried out with the objective of assessing the quality of groundwater in the Amaravathi basin, India, using a multiple indices approach. Groundwater quality data from 96 monitoring wells were obtained from the Central Groundwater Board and used in this study.
View Article and Find Full Text PDFChanging pattern of urban landscape and its impact on thermal environment of Lahore; Implications for climate change and sustainable development.
Environ Monit Assess
January 2025
College of Earth and Environmental Sciences, University of the Punjab, Lahore, 54000, Pakistan.
Rapid urbanization in Lahore has dramatically transformed land use and land cover (LULC), significantly impacting the city's thermal environment and intensifying climate change and sustainable development challenges. This study aims to examine the changes in the urban landscape of Lahore and their impact on the Urban thermal environment between 1990 and 2020. The previous studies conducted on Lahore lack the application of Geospatial artificial intelligence (GeoAI) to quantify land use and land cover, which is successfully covered in this study.
View Article and Find Full Text PDFThe effect of environmental factors on transepithelial potential in a model Amazonian teleost, the tambaqui (Colossoma macropomum): Implications for sodium balance in harsh environments.
J Fish Biol
January 2025
Laboratory of Ecophysiology and Molecular Evolution, Brazilian National Institute for Research of the Amazon (INPA), Manaus, Brazil.
The tambaqui (Colossoma macropomum, G. Cuvier 1818) thrives both in the ion-poor waters of the Amazon and in commercial aquaculture. In both, environmental conditions can be harsh due to low ion levels, occasional high salt challenges (in aquaculture), low pH, extreme PO levels (hypoxia and hyperoxia), high PCO levels (hypercapnia), high ammonia levels (in aquaculture), and high and low temperatures.
View Article and Find Full Text PDFStudy on the relationship among typhoon, weather change and acute ischemic stroke in southern Zhejiang Province of China.
BMC Neurol
January 2025
Department of Anesthesiology, The First Affiliated Hospital of Wenzhou Medical University, Ouhai District, Wenzhou, Zhejiang, China.
Objective: This study aimed to investigate the relationship between the unique weather change and acute ischemic stroke (AIS) in the southern Zhejiang Province of China and to provide evidence for better predicting and preventing stroke.
Methods: We retrospectively collected 14,996 ischemic stroke patients data and weather data from January 2019 to December 2021 in the southern Zhejiang Province of China. The correlation and risk between meteorological factors and the number of AIS daily cases were calculated.
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