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Ultrafast Preparation of High-Entropy NASICON Cathode Enables Stabilized Multielectron Redox and Wide-Temperature (-50-60 °C) Workability in Sodium-Ion Batteries.
Adv Mater
January 2025
MOE Key Laboratory for UV Light-Emitting Materials and Technology, Department of Physics, Northeast Normal University, Changchun, 130024, P. R. China.
Avoiding severe structural distortion, irreversible phase transition, and realizing the stabilized multielectron redox are vital for promoting the development of high-performance NASICON-type cathode materials for sodium-ion batteries (SIBs). Herein, a high-entropy NaVFeTiMnCr(PO) (HE-NaTMP) cathode material is prepared by ultrafast high-temperature shock, which inhibits the possibility of phase separation and achieves reversible and stable multielectron transfer of 2.4/2.
View Article and Find Full Text PDFDelayed Versus Atypical Speech Sound Development: A Markedness-Based Analysis of Speech Sound Disorder in Cantonese.
J Speech Lang Hear Res
January 2025
Division of Speech and Hearing Sciences, The University of Hong Kong, China.
Purpose: Speech sound disorder (SSD) is one of the major speech disorders in school-age children. Given the heterogeneity in terms of subtypes within SSD, there is a need to develop techniques for a quick identification of these subtypes. Furthermore, given the paucity of studies from children with SSD from Cantonese-speaking homes and a noted prevalence of SSDs in Cantonese-speaking children, it becomes even more important to investigate the subtypes of SSDs in Cantonese-speaking children.
View Article and Find Full Text PDFOptimal time-frequency localized wavelet filters for identification of Alzheimer's disease from EEG signals.
Cogn Neurodyn
December 2025
Department of Electrical and Electronics Engineering, Jazan, 45142 Jazan Saudi Arabia.
Alzheimer's disease (AD) is a chronic disability that occurs due to the loss of neurons. The traditional methods to detect AD involve questionnaires and expensive neuro-imaging tests, which are time-consuming, subjective, and inconvenient to the target population. To overcome these limitations, Electroencephalogram (EEG) based methods have been developed to classify AD patients from normal controlled (NC) and mild cognitive impairment (MCI) subjects.
View Article and Find Full Text PDFAdjunctive Fresh Frozen Plasma Versus Adjunctive Cryoprecipitate in Cardiac Surgery Patients Receiving Platelets for Perioperative Bleeding.
J Cardiothorac Vasc Anesth
December 2024
Department of Critical Care, University of Melbourne, Parkville, Australia; Department of Intensive Care, Austin Hospital, Melbourne, Victoria, Australia; Australian and New Zealand Intensive Care Research Centre, Monash University, Melbourne, Australia; Department of Intensive Care, Royal Melbourne Hospital, Melbourne, Australia; Data Analytics Research and Evaluation Centre, Austin Hospital, Melbourne, Australia.
Objective(s): This study was designed to assess the relative association between adjunctive fresh frozen plasma (FFP) or adjunctive cryoprecipitate and morbidity and mortality in cardiac surgery patients receiving platelets for perioperative bleeding.
Design: Retrospective cohort study using inverse probability of treatment weighting with entropy balancing.
Setting: Multi-institutional study of 58 centers using the Australian and New Zealand Society of Cardiac and Thoracic Surgeons National Cardiac Surgery Database from January 1, 2005, to December 31, 2021.
Understanding Catalyst 'Volcano' Dependence Through Fermi-Level Controlled Kinetics Using Electronic Theory.
Entropy (Basel)
November 2024
Catalysis and Transient Kinetics Group, Idaho National Laboratory, Idaho Falls, ID 83415, USA.
The ubiquitous two-step Michaelis-Menten and Temkin-Boudart reaction mechanisms are extended to include the influence of the catalyst electronic subsystem in a 5-step mechanism. The resulting kinetic equation provides an alternative explanation for the well-known volcano-shaped dependence found in catalysis. The equilibrium constants of fast electronic steps are highlighted for their influence on adsorption and desorption through the relative concentration of charged versus neutral intermediates.
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