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Flaky sputtered silicon MWCNTs core-shell structure as a freestanding binder-free electrode for lithium-ion battery.

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Nano-fabricated Energy Devices Lab, School of Electrical and Computer Eng., University of Tehran, 14395-515, Tehran, Iran.

Core-shell silicon/multiwall carbon nanotubes are one of the most promising anode candidates for further improvement of lithium-ion batteries. Sufficient accommodation for massive volume expansion of silicon during the lithiation process and preventing pulverization and delamination with easy fabrication processes are still critical issues for practical applications. In this study, core-shell silicon/MWCNTs anode materials were synthesized using a facile and controllable PECVD technique to realize aligned MWCNTs followed by a silicon sputtering step.

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The purpose of this study is to analyze the large deflection problem of bimodular functionally graded truncated thin conical shells under the transverse mechanical load and non-uniform thermal load, in which two different boundary constraints of the truncated shell with two ends simply supported and fully fixed are considered. It is assumed that the temperature distribution along the thickness direction satisfies the Fourier law of heat transfer, and the material properties change exponentially along the thickness direction while different properties in tension and compression are considered. The geometric equation of the conical shell is established based on the equivalent method of curvature correction of von-Kármán deformation theory, and the analytical solution of the problem is obtained by Ritz method.

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