Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1103/physrevb.46.12810 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Hydrodynamic cavitation induced fabrication of soy protein isolate-polyphenol complexes: Structural and functional properties.
Curr Res Food Sci
January 2025
School of Biological and Chemical Engineering, Guangxi University of Science and Technology, Guangxi Key Laboratory of Green Processing of Sugar Resources, Key Laboratory for Processing of Sugar Resources of Guangxi Higher Education Institutes, Liuzhou, 545006, China.
The combination of polyphenols and protein can improve the functional characteristics of protein. How to effectively promote the binding of polyphenols to protein is still a difficult topic. In this study, hydrodynamic cavitation (HC) was used to induce the fabrication of complexes between soy protein isolate (SPI) and different polyphenols (tannic acid (TA), chlorogenic acid (CGA), ferulic acid (FA), caffeic acid (CA), and gallic acid (GA)).
View Article and Find Full Text PDFA stereochemical model and origins of selectivity for the rhodium-catalyzed hydroselenation of styrene.
Dalton Trans
January 2025
Chongqing Key Laboratory of Green Catalysis Materials and Technology, College of Chemistry, Chongqing Normal University, Chongqing 401331, China.
A deeper understanding of the mechanisms underlying transition metal-catalyzed transformation is crucial for developing innovative strategies to synthesize chiral organoselenium compounds. In this study, we developed and investigated a three-layer chirality relay model for the rhodium-catalyzed asymmetric hydroselenation of alkenes through density functional theory (DFT) calculations. In the back layer of this model, the four bulky substituents on the phosphorus atom of the bidentate chiral MeO-BIPHEP ligand were positioned on axial and equatorial bonds, thereby influencing the configuration of the middle layer.
View Article and Find Full Text PDFConstruction of organic heterojunctions as metal-free photocatalysts for enhancing water splitting and phenol degradation by regulating charge flow.
Mater Horiz
January 2025
School of Chemistry and Materials Science, Hangzhou Institute for Advanced Study University of Chinese Academy of Sciences, Hangzhou, 310024, P. R. China.
Metal-free photocatalysts derived from earth-abundant elements have drawn significant attention owing to their ample supply for potential large-scale applications. However, it is still challenging to achieve highly efficient photocatalytic performance owing to their sluggish charge separation and lack of active catalytic sites. Herein, we designed and constructed a series of covalently bonded organic semiconductors to enhance water splitting and phenol degradation.
View Article and Find Full Text PDFMechanochemical Synthesis of Type III Porous Liquids from Solid Precursors for the Removal and Conversion of Waste CO from CH.
Adv Mater
January 2025
State Key Laboratory of Coordination Chemistry, Key Laboratory of Mesoscopic Chemistry of MOE, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, P. R. China.
Porous liquids (PLs) have emerged as a promising class of flow porous materials, offering distinctive benefits for sustainable separation processes coupled with catalytic transformations in the chemical industry. Despite their potential, challenges remain in the realms of synthesis complexity, stability, and the strategic engineering of separation and catalytic sites. In this study, a scalable mechanochemical synthetic approach is reported to fabricate Type III PLs from solid precursors with high stability.
View Article and Find Full Text PDFLight-Induced Transformation from Covalent to Supramolecular Polymer Networks.
ACS Macro Lett
January 2025
School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai 200240, P. R. China.
Stimuli-responsive polymers have demonstrated significant potential in the development of smart materials due to their capacity to undergo targeted property changes in response to external physical or chemical stimuli. However, the scales of response in most existing stimuli-responsive polymer systems are mainly focused on three levels: functional units, chain conformations, or polymer topologies. Herein, we have developed a covalent polymer network (CPN) capable of converting into a supramolecular polymer network (SPN) within bulk materials directly at the scale of polymer network types.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!