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Effect of rPET Content and Preform Heating/Cooling Conditions in the Stretch Blow Molding Process on Microcavitation and Solid-State Post-Condensation of vPET-rPET Blend: Part II-Statistical Analysis and Interpretation of Tests.
Materials (Basel)
December 2024
Faculty of Physics and Astronomy, University of Wroclaw, 9 Maxa Born Square, 50-204 Wroclaw, Poland.
This research explores how varying proportions of virgin polyethylene terephthalate (vPET) and recycled polyethylene terephthalate (rPET) in vPET-rPET blends, combined with preform thermal conditions during the stretch blow molding (SBM) process, influence PET bottles' microscopic characteristics. Key metrics such as viscosity, density, crystallinity, amorphous phase relaxation, and microcavitation were assessed using response surface methodology (RSM). Statistical analysis, including Analysis of variance (ANOVA) and its power, supported the interpretation of results.
View Article and Find Full Text PDFDevelopment and evaluation of a polymer material-based formulation for non-surgical nasolabial fold reduction.
Int J Cosmet Sci
January 2025
Makeup Products Research, Kao Corporation, Odawara, Japan.
Objective: Currently, nasolabial folds are mainly removed by invasive procedures, resulting in long-lasting changes, as non-surgical user-implementable alternatives are scarce and inefficient. For example, the use of coating films for this purpose has thus far faced substantial difficulties because such films should combine the antithetical properties of shrinkability and flexibility. Herein, we challenge this status quo by identifying a polymer that simultaneously exhibits shrinkability and flexibility and using this polymer to develop a cosmetic formulation for immediate and non-invasive nasolabial fold removal.
View Article and Find Full Text PDFPacking Engineering of Zirconium Metal-Organic Cages in Mixed Matrix Membranes for CO2/CH4 Separation.
Angew Chem Int Ed Engl
January 2025
National University of Singapore, Department of Chemical and Biomolecular Engineering, 4 Engineering Drive 4, Blk E5, #02-16, 117585, Singapore, SINGAPORE.
Metal-organic cages (MOCs) have been considered as emerging zero-dimensional (0D) porous fillers to generate molecularly homogenous MOC-based membrane materials. However, the discontinuous pore connectivity and low filler concentrations limit the improvement of membrane separation performance. Herein, we propose the dimension augmentation of MOCs in membranes using three-dimensional (3D) supramolecular MOC networks as filler materials in mixed matrix membranes (MMMs).
View Article and Find Full Text PDFCurrent Positron Studies on the Modifications of the Molecular Packing in Green-Based Polymers Through Changes in the Synthesis Procedures or Environmental Conditions.
Polymers (Basel)
December 2024
Positron Group "Prof. Alfredo Dupasquier", Faculty of Exact Sciences, Tandil Institute of Materials Physics (IFIMAT), National University of the Center of the Buenos Aires Province (UNCPBA), Pinto 399, 7000 Tandil, Argentina.
The sensitivity of positron annihilation characteristics to changes in the molecular packing in network-forming polymers has been demonstrated since the early 1980s. Positron annihilation lifetime spectroscopy (PALS) is a unique technique that can provide direct information on the free volume in polymers through the experimental parameters of the free volume hole distribution, their mean value, and volume fraction. This knowledge is currently applied for PALS investigations on the main processes that govern the molecular organization in some green polymers when subjected to different synthesis procedures or environmental conditions (humidity, physical aging, temperature).
View Article and Find Full Text PDFStudy of Water Resistance of Polyurethane Coatings Based on Microanalytical Methods.
Polymers (Basel)
December 2024
Civil Engineering Department, Lanzhou Jiaotong University, Lanzhou 730070, China.
This study investigates the effect of microstructural changes in polyurethane coatings on their water resistance properties. Polyurethane coatings with varying diluent contents were prepared and tested for water penetration resistance and mechanical property retention. The time-dependent behavior of water within the coatings at different immersion durations was analyzed using low-field nuclear magnetic resonance (NMR).
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