Femtosecond laser-induced nano- and microstructuring of Cu electrodes for CO electroreduction in acetonitrile medium.

The dependency of CO reduction rate in acetonitrile-BuNClO solution on cathodes, which were modified by laser induction of a copper surface, was studied. The topography of laser-induced periodic surface structures (LIPSS) → grooves → spikes was successively formed by a certain number of pulses. It was proved that for a higher number of laser pulses, the surface area of the copper cathode increases and preferred platy orientation of the copper surface on [022] crystallografic direction and larger fluence values increase.

Synthesis of silver nanoparticles by sonogalvanic replacement on aluminium powder in sodium polyacrylate solutions.

The process of the formation of silver nanoparticles (AgNPs) via the method of galvanic replacement (GR) of Ag with aluminum powder in sodium polyacrylate (NaPA) solutions in the ultrasonic (US) field has been studied. It was observed, that the yellow colloidal solutions of stabilized AgNPs with the absorption maximum at ∼ 410 nm were obtained under the application of US power by 20 W and frequency by 20 kHz in the wide range of AgNO and NaPA concentrations (0.1 - 0.

Microplasma Synthesis of Antibacterial Active Silver Nanoparticles in Sodium Polyacrylate Solutions.

The great demand for functional, particularly biologically active, metal nanoparticles has led to the search for technologically effective, green, and controlled methods of synthesizing these metal nanoparticles. Plasma glow discharge is one of the most promising techniques in this direction. The results of studies based on the synthesis of colloidal solutions of stabilized silver nanoparticles (AgNPs) by the microplasma method in solutions of a nontoxic surfactant sodium polyacrylate (NaPA) are presented.