Odd-Numbered Ring Cluster Tc(μ-O)Cl(OOCCCl): Synthesis, Crystal Structure, and Optical and Thermal Properties.

Herein, we report a method for the preparation of the first odd homometallic and heterovalent nine-centered Tc wheel, [Tc(μ-O)Cl(OOCCl)]. The synthesized compound represents the pioneering instance of such clusters among d elements and is the fourth instance observed across all metals. The ring was synthesized by a solvothermal method in a solution of technetium acid in trichloroacetic anhydride.

Difference in the Catalytic Activity of Atoms in the Corners and at the Edges of Gold Nanoparticles: Hydrogen Isotope Exchange Reaction.

The goal of this work is to investigate the catalytic activities of low-coordination atoms located in gold nanoparticles. Gold nanoparticles with sizes from 0.7 to 40 nm deposited on γ-AlO were used as a catalyst.

Synthesis of Technetium Carboxylates: Wheel-Like Octanuclear Clusters (Tc(μ-O)(RCOO), Where R = CF, CH)─Potential Nanobuilding Units for Tc-MOFs.

Herein, we studied the behavior of TcO in trifluoroacetic anhydride (TFAA) under visible light irradiation in situ by UV-vis spectroscopy. One carboxylate of Tc(VII) CFOTc () and two wheel-like carboxylate clusters of Tc(IV) Tc(μ-O)(CFCOO) (, ) and Tc(μ-O)(CHCOO) () were synthesized and analyzed using pXRD, TGA, UV-vis spectroscopy, and SCXRD techniques. According to SCXRD, it was found that Tc(IV) trifluoroacetate exists in two crystalline modifications.

Microwave-Assisted Synthesis of Water-Dispersible Humate-Coated Magnetite Nanoparticles: Relation of Coating Process Parameters to the Properties of Nanoparticles.

Nowadays, there is a demand in the production of nontoxic multifunctional magnetic materials possessing both high colloidal stability in water solutions and high magnetization. In this work, a series of water-dispersible natural humate-polyanion coated superparamagnetic magnetite nanoparticles has been synthesized via microwave-assisted synthesis without the use of inert atmosphere. An impact of a biocompatible humate-anion as a coating agent on the structural and physical properties of nanoparticles has been established.

Adsorption of ozone and plasmonic properties of gold hydrosol: the effect of the nanoparticle size.

The impact of the size of gold nanoparticles on the magnitude of the bathochromic shift of their plasmon resonance peak upon ozone adsorption is revealed and analyzed. Namely, the plasmon band position of 7, 10, 14 and 32 nm nanoparticles shifts toward longer wavelengths by 51, 35, 23 and 9 nm respectively, i.e.