Colloidal ionogels: Controlled assembly and self-propulsion upon tunable swelling.

Active colloids driven out of thermal equilibrium serve as building blocks for smart materials with tunable structures and functions. Using chemical energy to drive colloids is advantageous but requires precise control over chemical release. To address this, we developed colloidal ionogels-polymer microspheres infused with ionic liquids-that show controlled assembly and self-propulsion upon tunable swelling.

A Conceptual Framework to Understand the Self-Assembly of Chemically Active Colloids.

Colloids that generate chemicals, or "chemically active colloids", can interact with their neighbors and generate patterns via forces arising from such chemical gradients. Examples of such assemblies of chemically active colloids are abundant in the literature, but a unified theoretical framework is needed to rationalize the scattered results. Combining experiments, theory, Brownian dynamics, and finite element simulations, we present here a conceptual framework for understanding how immotile, yet chemically active, colloids assemble.

Chemical Micromotors Move Faster at Oil-Water Interfaces.

Many real-world scenarios involve interfaces, particularly liquid-liquid interfaces, that can fundamentally alter the dynamics of colloids. This is poorly understood for chemically active colloids that release chemicals into their environment. We report here the surprising discovery that chemical micromotors─colloids that convert chemical fuels into self-propulsion─move significantly faster at an oil-water interface than on a glass substrate.

Electroosmotic flow spin tracers near chemical nano/micromotors.

We report the first experimental observation of tracer spinning in place alongside chemically powered individual nano/micromotors. The torques are primarily generated by the electroosmotic flow on the motor surface. Such spinning is observed in various combinations of nano/micromotors and tracers of different shapes, sizes and chemical compositions.

Ultrasonic Steering Wheels: Turning Micromotors by Localized Acoustic Microstreaming.

The ability to steer micromotors in specific directions and at precise speeds is highly desired for their use in complex environments. However, a generic steering strategy that can be applied to micromotors of all types and surface coatings is yet to be developed. Here, we report that ultrasound of ∼100 kHz can spin a spherical micromotor so that it turns left or right when moving forward, or that it moves in full circles.