The thermal, rheological, and mechanical behavior of copolymers of lactide, isosorbide, and three different phthalic acids are studied in a wide range of compositions. A linear behavior in glass transition temperature (Tg) with respect to the mole fraction of isosorbide and phthalate content in the copolymers is observed. This behavior is in quantitative agreement with the well-known Di Marzio-Gibbs equation, which correlates the Tg with the mole fraction of flexible bonds in the monomers.
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