Compositional Optimization of Sputtered WO/MoO Films for High Coloration Efficiency.

Thin films of mixed MoO and WO were obtained using reactive magnetron sputtering onto ITO-covered glass, and the optimal composition was determined for the best electrochromic (EC) properties. A combinatorial material synthesis approach was applied throughout the deposition experiments, and the samples represented the full composition range of the binary MoO/WO system. The electrochromic characteristics of the mixed oxide films were determined with simultaneous measurement of layer transmittance and applied electric current through the using organic propylene carbonate electrolyte cells in a conventional three-electrode configuration.

Composite ligand shells on gold nanoprisms - an ensemble and single particle study.

The attachment of thiolated molecules onto gold surfaces is one of the most extensively used and robust ligand exchange approaches to exploit the nanooptical features of nanoscale and nanostructured plasmonic materials. In this work, the impact of thiol adsorption on the optical properties of wet-chemically synthesized gold nanoprisms is studied both at the ensemble and single particle level to investigate the build-up of more complex ligand layers. Two prototypical ligands with different lengths have been investigated ((16-mercaptohexadecyl)trimethylammonium bromide - MTAB and thiolated polyethylene glycol - mPEG-SH).

Investigation of Combinatorial WO-MoO Mixed Layers by Spectroscopic Ellipsometry Using Different Optical Models.

Reactive (Ar-O plasma) magnetron sputtered WO-MoO (nanometer scaled) mixed layers were investigated and mapped by Spectroscopic Ellipsometry (SE). The W- and Mo-targets were placed separately, and 30 × 30 cm glass substrates were slowly moved under the two (W and Mo) separated targets. We used different (oscillator- and Effective Medium Approximation, EMA-based) optical models to obtain the thickness and composition maps of the sample layer relatively quickly and in a cost-effective and contactless way.

Micro-combinatorial sampling of the optical properties of hydrogenated amorphous [Formula: see text] for the entire range of compositions towards a database for optoelectronics.

The optical parameters of hydrogenated amorphous a-[Formula: see text]:H layers were measured with focused beam mapping ellipsometry for photon energies from 0.7 to 6.5 eV.

Nanosecond resistive switching in Ag/AgI/PtIr nanojunctions.

Nanometer-scale resistive switching devices operated in the metallic conductance regime offer ultimately scalable and widely reconfigurable hardware elements for novel in-memory and neuromorphic computing architectures. Moreover, they exhibit high operation speed at low power arising from the ease of the electric-field-driven redistribution of only a small amount of highly mobile ionic species upon resistive switching. We investigate the memristive behavior of a so-far less explored representative of this class, the Ag/AgI material system in a point contact arrangement established by the conducting PtIr tip of a scanning probe microscope.

Target dependent femtosecond laser plasma implantation dynamics in enabling silica for high density erbium doping.

Chemical dissimilarity of tellurium oxide with silica glass increases phase separation and crystallization tendency when mixed and melted for making a glass. We report a novel technique for incorporating an Er(3+)-doped tellurite glass composition into silica substrates through a femtosecond (fs) laser generated plasma assisted process. The engineered material consequently exhibits the spectroscopic properties of Er(3+)-ions, which are unachievable in pure silica and implies this as an ideal material for integrated photonics platforms.

Expression platforms for producing eukaryotic proteins: a comparison of E. coli cell-based and wheat germ cell-free synthesis, affinity and solubility tags, and cloning strategies.

Vectors designed for protein production in Escherichia coli and by wheat germ cell-free translation were tested using 21 well-characterized eukaryotic proteins chosen to serve as controls within the context of a structural genomics pipeline. The controls were carried through cloning, small-scale expression trials, large-scale growth or synthesis, and purification. Successfully purified proteins were also subjected to either crystallization trials or (1)H-(15)N HSQC NMR analyses.

The Center for Eukaryotic Structural Genomics.

The Center for Eukaryotic Structural Genomics (CESG) is a "specialized" or "technology development" center supported by the Protein Structure Initiative (PSI). CESG's mission is to develop improved methods for the high-throughput solution of structures from eukaryotic proteins, with a very strong weighting toward human proteins of biomedical relevance. During the first three years of PSI-2, CESG selected targets representing 601 proteins from Homo sapiens, 33 from mouse, 10 from rat, 139 from Galdieria sulphuraria, 35 from Arabidopsis thaliana, 96 from Cyanidioschyzon merolae, 80 from Plasmodium falciparum, 24 from yeast, and about 25 from other eukaryotes.

New bioinformatics resources for metabolomics.

We recently developed two databases and a laboratory information system as resources for the metabolomics community. These tools are freely available and are intended to ease data analysis in both MS and NMR based metabolomics studies. The first database is a metabolomics extension to the BioMagResBank (BMRB, http://www.

Project management system for structural and functional proteomics: Sesame.

A computing infrastructure (Sesame) has been designed to manage and link individual steps in complex projects. Sesame is being developed to support a large-scale structural proteomics pilot project. When complete, the system is expected to manage all steps from target selection to data-bank deposition and report writing.