Few-cycle laser pulse characterization on-target using high-harmonic generation from nano-scale solids.

We demonstrate high-harmonic generation for the time-domain observation of the electric field (HHG-TOE) and use it to measure the waveform of ultrashort mid-infrared (MIR) laser pulses interacting with ZnO thin-films or WS monolayers. The working principle relies on perturbing HHG in solids with a weak replica of the pump pulse. We measure the duration of few-cycle pulses at 3200 nm, in reasonable agreement with the results of established pulse characterization techniques.

Photo-ionization initiated differential ultrafast charge migration: impacts of molecular symmetries and tautomeric forms.

Photo-ionization induced ultrafast electron dynamics is considered as a precursor for the slower nuclear dynamics associated with molecular dissociation. Here, using the multielectron wave-packet propagation method, we study the overall many-electron dynamics, triggered by ionizing the outer-valence orbitals of different tautomers for a prototype molecule with more than one symmetry element. From the time evolution of the initially created averaged hole density of each system, we identify distinctly different charge dynamics responses in the tautomers.