From nanotubes to nanoholes: Scaling of selectivity in uniformly charged nanopores through the Dukhin number for 1:1 electrolytes.

Scaling of the behavior of a nanodevice means that the device function (selectivity) is a unique smooth and monotonic function of a scaling parameter that is an appropriate combination of the system's parameters. For the uniformly charged cylindrical nanopore studied here, these parameters are the electrolyte concentration, c, voltage, U, the radius and the length of the nanopore, R and H, and the surface charge density on the nanopore's surface, σ. Due to the non-linear dependence of selectivities on these parameters, scaling can only be applied in certain limits.