State-of-the-art phosphorylation of water-soluble allyl cellulose via a green radical-mediated "click" reaction pathway with enhanced antifungal activity.

Allyl Cellulose (AC) was synthesized using allyl bromide in sodium hydroxide (NaOH)/urea aqueous solution. By employing a molar ratio of 6:1 of allyl bromide/cellulose, low-degree of substitution (DS) water-soluble AC (AC) was obtained (DS = 0.67).

Biomimetic poly(methyl methacrylate)-based terpolymers: modulation of bacterial adhesion effect.

Adherence of Staphylococcus aureus, responsible for major foreign body infections, was assessed onto functionalized poly(methyl methacrylate)-based terpolymers bearing sulfonate and carboxylate groups and onto poly(methyl methacrylate) as control. These terpolymers, have been synthesized by radical copolymerization of methyl methacrylate, methacrylic acid, and sodium styrene sulfonate by varying the ratio R = [COO(-)]/[COO(-) + SO(3)(-)] from 0 to 1 and keeping ionic monomer content between 7 and 18%. Adsorption of fibronectin onto poly(methyl methacrylate) was shown to dramatically promote bacterial adherence, whereas a strong inhibition of bacteria adherence was observed onto functionalized terpolymers containing both carboxylate and sulfonate groups.