Modulating Electrochemical Energy Storage and Multi-Spectra Defense of MXenes by Interfacial Dual-Filler Engineering.

MXenes have attracted growing interest in electrochemical energy storage owing to their high electronic conductivity and editable surface chemistry. Besides, rendering MXenes with spectrum defense properties further broadens their versatile applications. However, the development of MXenes suffers from weak van der Waal interaction-driven self-restacking that leads to random alignment and inferior interface microenvironments.

Ultrasensitive Bio-HS Gas Sensor Based on CuO-MWCNT Heterostructures.

Developing a respiratory analysis disease diagnosis platform for the HS biomarker has great significance for the real-time detection of various diseases. However, achieving highly sensitive and rapid detection of HS gas at the parts per billion level at low temperatures is one of the most critical challenges for developing portable exhaled gas sensors. Herein, CuO-multiwalled carbon nanotube (MWCNT) heterostructures with excellent gas sensitivity to HS at room temperature and a lower temperature were successfully synthesized by a facile two-dimensional (2D) electrodeposition in situ assembly method.

Double Modification of Poly(urethane-urea): Toward Healable, Tear-Resistant, and Mechanically Robust Elastomers for Strain Sensors.

Polyurethane elastomers with mechanical robustness, tear resistance, and healing efficiency hold great potential in wearable sensors and soft robots. However, achieving excellent mechanical properties and healable capability simultaneously remains highly desirable but exclusive. Herein, we propose a straightforward procedure for double modification of poly(urethane-urea) (PUU) via thiolactone chemistry, and two different dynamic cross-linking bonds (disulfide linkages and Zn/imidazole coordination) are successively incorporated into the side chain of PUU, producing double cross-linking elastomers (PUU-I/Zn-S).

A flexible, robust and multifunctional montmorillonite/aramid nanofibers@MXene electromagnetic shielding nanocomposite with an alternating structure for enhanced Joule heating and fire-resistant protective performance.

With the rapidly increasing development of portable devices and flexible electronic devices, multifunctional composites with excellent mechanical strength, great electromagnetic interference shielding, great Joule heating performance and strong fire-resistant protective performance are noticeably required. Herein, inspired by the sandwich structure, we have designed a montmorillonite/aramid nanofibers@MXene (MMT/ANFs@MXene) nanocomposite with an alternating multilayered structure a simple AVF process. In this nanocomposite, the ANFs/MMT (AT) layer acts as a mechanically reinforced and insulation protection layer, while the MXene layer maintains a complete conductive network.

Healable Strain Sensor Based on Tough and Eco-Friendly Biomimetic Supramolecular Waterborne Polyurethane.

Stretchable sensors are essential for flexible electronics, which can be made with polymer elastomers as the matrix. The main challenge in producing practical devices is to obtain polymers with mechanical stability, eco-friendliness, and self-healing properties. Herein, we introduce urea bonds and 2-ureido-4[1]-pyrimidinone (UPy) to synthesize tailored waterborne polyurethanes (WPU-UPy-) with a hierarchical hydrogen bond (H-bond).

Preparation of Poly(thiol-urethane) Covalent Adaptable Networks Based on Multiple-Types Dynamic Motifs.

To solve the issue of polymeric materials recycling, developing intrinsic self-healing materials containing dynamic bonds has attracted many researchers' highly concerning. However, the tradeoff between their mechanical strength and stretchability always does not avoid. Herein, to surmount the above tradeoff, metal-ligand (Cu -S) interactions are introduced into the cross-linking polythiourethane covalent adaptable networks (PTU CANs) with three kinds of dynamic motifs (thiourethane, disulfide, and hydrogen bonds).

Conductive Antibacterial Hemostatic Multifunctional Scaffolds Based on TiCT MXene Nanosheets for Promoting Multidrug-Resistant Bacteria-Infected Wound Healing.

Chronic bacterial-infected wound healing/skin regeneration remains a challenge due to drug resistance and the poor quality of wound repair. The ideal strategy is combating bacterial infection, while facilitating satisfactory wound healing. However, the reported strategy hardly achieves these two goals simultaneously without the help of antibiotics or bioactive molecules.

Hydrogen Bonding-Derived Healable Polyacrylate Elastomers via On-demand Copolymerization of n-Butyl Acrylate and tert-Butyl Acrylate.

Achieving a desirable combination of good mechanical properties and healing efficiency is a great challenge in the development of self-healing elastomers. Herein, a class of tough and strong self-healing polyacrylate elastomers (denoted as HPs) was developed simply by free-radical copolymerization of n-butyl acrylate (nBA) and tert-butyl acrylate (tBA) and a subsequent hydrolysis reaction rather than direct copolymerization of nBA and acrylic acid (AA). The tiny difference in reactivity between nBA and tBA makes the structural units of the copolymer easy to control.