Black-to-transparent electrochromism is hailed as the holy grail of organic optoelectronics. Despite its potential, designing black electrochromic materials that fully absorb visible light remains a significant challenge. Electroactive materials that simultaneously possess excellent cyclic stability, fast switching times, and high coloration efficiency are rare.
View Article and Find Full Text PDFAll-solid-state lithium-ion batteries (ASSLIBs) have attracted much attention owing to their high energy density and safety and are known as the most promising next-generation LIBs. The biggest advantage of ASSLIBs is that it can use lithium metal as the anode without any safety concerns. This study used a high-conductivity garnet-type solid electrolyte (LiLaZrTaO, LLZTO) and Li-Ga-N composite anode synthesized by mixing melted Li with GaN.
View Article and Find Full Text PDFAll-solid-state Li-ion batteries (ASSLIBs), also known as next-generation batteries, have attracted much attention due to their high energy density and safety. The best advantage of ASSLIBs is the Li-metal anodes that could be used without safety issues. In this study, a highly conductive garnet solid electrolyte (LiLaZrTaO, LLZTO) was used in the ASSLIB, and a Pt film was used to modify the surface of LLZTO to prove the solution of the Li-metal anode for LLZTO.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2021
An effective Ru/CNT electrocatalyst plays a crucial role in solid-state lithium-carbon dioxide batteries. In the present article, ruthenium metal decorated on a multi-walled carbon nanotubes (CNTs) is introduced as a cathode for the lithium-carbon dioxide batteries with LiAlGe(PO) solid-state electrolyte. The Ru/CNT cathode exhibits a large surface area, maximum discharge capacity, excellent reversibility, and long cycle life with low overpotential.
View Article and Find Full Text PDFIn this study, we propose a top-down approach for the controlled preparation of undercoordinated Ni-N (Ni-hG) and Fe-N (Fe-hG) catalysts within a holey graphene framework, for the electrochemical CO reduction reaction (CORR) to synthesis gas (syngas). Through the heat treatment of commercial-grade nitrogen-doped graphene, we prepared a defective holey graphene, which was then used as a platform to incorporate undercoordinated single atoms carbon defect restoration, confirmed by a range of characterization techniques. We reveal that these Ni-hG and Fe-hG catalysts can be combined in any proportion to produce a desired syngas ratio (1-10) across a wide potential range (-0.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2021
ACS Appl Mater Interfaces
October 2020
Li metal, which has a high theoretical capacity and negative electrochemical potential, is regarded as the "holy grail" in Li-ion batteries. However, the flammable nature of liquid electrolyte leads to safety issues. Hence, the cooperation of solid-state electrolyte and Li-metal anode is demanded.
View Article and Find Full Text PDFThe marriage between a Li metal anode and the solid-state electrolyte is expected to limit the safety risk of secondary batteries. However, dendrites and interfacial stability hinder the combination of Li metal anode and solid-state electrolyte. Herein, a plastic crystal electrolyte (PCE) and three-dimensional (3D) host structure played the role of a matchmaker in combining the solid-state electrolyte and Li metal anode.
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