U-shaped association between 25-hydroxyvitamin D concentration and the prevalence of asthma in the overweight and obese U.S. population.

Introduction: Vitamin D supplementation has shown promise in averting asthma. However, the association between 25(OH)D levels and asthma prevention in various demographic groups remains inconclusive. Here, we explore this relationship in the context of overweight and obese individuals in the United States.

Induced Circular Dichroism of Isotactic Poly(2-vinylpyridine) with Diverse and Tunable "Sergeants-and-Soldiers" Type Chiral Amplification.

Facile and efficient construction of the helical structure with diverse and tunable chiral amplification from an achiral polymer is attractive but remains a challenge to develop multiple functional materials. We report herein a macromolecular acid-base complex of highly isotactic poly(2-vinylpyridine) ( > 99%), (+)-camphorsulfonic acid, and dodecylbenzensulfonic acid. The asymmetric induction of the chiral additive through the ionic interactions between pyridinium pendants and acid ions drives the polymer backbone to twist in a preferred direction in CHCl and its mixture with CHCN.

Enantiomer-selective magnetization of conglomerates for quantitative chiral separation.

Selective crystallization represents one of the most economical and convenient methods to provide large-scale optically pure chiral compounds. Although significant development has been achieved since Pasteur's separation of sodium ammonium tartrate in 1848, this method is still fundamentally low efficient (low transformation ratio or high labor). Herein, we describe an enantiomer-selective-magnetization strategy for quantitatively separating the crystals of conglomerates by using a kind of magnetic nano-splitters.