Publications by authors named "Zhuyu Sun"

Lindane is a broad-spectrum organochlorine insecticide which has been included in the persistent organic pollutants (POPs) list together with its two hexachlorocyclohexane (HCH) isomers. Due to its continuous use in the past decades, the environmental impacts of HCHs are still severe now. Therefore, in the present study, dielectric barrier discharge (DBD) plasma was used as an advanced oxidation process for the destruction of HCHs in water.

View Article and Find Full Text PDF

Glucocorticoids (GCs) have drawn great concern due to their widespread contamination in the environment and application in treating patients with COVID-19. Due to the lack of data about GC removal using advanced treatment processes, a novel Paralleling and bubbling corona discharge reactor (PBCD) combined with iron-loaded activated-carbon fibre (Fe-ACF) was addressed in this study to degrade GCs represented by Hydrocortisone (HC) and Betamethasone (BT). The results showed that the PBCD-based system can degrade GCs effectively and can achieve effective sterilization.

View Article and Find Full Text PDF

Non-thermal plasma (NTP) technology is an emerging advanced oxidation process, which has shown excellent performances in soil organic pollution remediation. Dissolved organic matter (DOM) is one of the most important components in soil, however, investigations on the structural and compositional changes of DOM during NTP process are lacking. Therefore, in the present study, we systematically investigated the soil DOM changes under different discharge voltages, atmospheres or soils with different moisture contents.

View Article and Find Full Text PDF

As an emerging class of organic contaminants, polyhalogenated carbazoles (PHCZs) have been increasingly detected all over the world since 1980s. Due to the environmental persistence, bioaccumulation, and dioxin-like toxicity, PHCZs have aroused widespread concerns in recent years. However, efficient approach for the degradation of PHCZs is quite limited so far.

View Article and Find Full Text PDF

Perfluorooctanoic acid (PFOA) poses a serious threat to the ecological environment and biological health because of its ubiquitous distribution, extreme persistence, and high toxicity. In this study, we designed a novel gas-liquid dielectric barrier discharge (GLDBD) reactor which could efficiently destruct PFOA. PFOA removal efficiencies can be obtained in various water matrices, which were higher than 98.

View Article and Find Full Text PDF

Efficient destruction of perfluoroalkyl compounds in contaminated waters remains a challenge because of highly stable C-F bonds. In this study, mineralization of perfluorooctanoic acid (PFOA) with high concentration (∼30 mg/L) was realized in a needle-plate pulsed discharge reactor integrated with a water jet (NPDW) to which microbubbles (MBs) with different carrier gases (air, N, and Ar) were introduced to enhance interfacial reactions. MBs effectively enrich dispersed PFOA from a bulk solution to a liquid surface to allow enhancing contact with reactive species and also expanding the plasma discharge area and channels.

View Article and Find Full Text PDF

The applications of photocatalytic pollutant degradation have remained limited due to the low efficiency of solar energy utilization. In this study, a photothermal catalyst consisting of reduced graphene oxide @ black TiO (RGO@BT) nanofluid with effective full-spectrum (from ultraviolet to infrared light) absorption was synthesized by a typical two-step method of high temperature calcination and hydrothermal method. Moreover, the photothermal catalytic performance of the RGO@BT nanofluid on tetracycline was verified.

View Article and Find Full Text PDF

Perfluorooctanoic acid (PFOA) from contaminated soil accumulates in higher organisms, and causes health risks to humans. In this research, 71 % of the PFOA was degraded, of which 51 % was decomposed into short chain by-products, 19 % mineralized, and 1 % volatilized with 30 kV of voltage, 50 Hz of discharge frequency, 1 % of soil moisture, 300 ppm of PFOA concentration and 6.3 of soil pH using pulsed positive discharge plasma.

View Article and Find Full Text PDF

Traditional seed pretreatment methods cause secondary pollution for the application of various chemicals. This study investigated the effect of dielectric barrier discharge (DBD) cold plasma on seedling growth. Effects of plasma-activated tap water (PATW) and plasma-activated seeds (PAS) were compared for germination rates, seedling height, dry weight, and chlorophyll content.

View Article and Find Full Text PDF

Perfluorooctanesulfonate (PFOS) is a toxic, bioaccumulative, and highly persistent anthropogenic chemical. Hydrated electrons ( e) are potent nucleophiles that can effectively decompose PFOS. In previous studies, e are mainly produced by photoionization of aqueous anions or aromatic compounds.

View Article and Find Full Text PDF

Iodide photolysis under UV illumination affords an effective method to produce hydrated electrons (e) in aqueous solution. Therefore, UV/Iodide photolysis can be utilized for the reductive degradation of many recalcitrant pollutants. However, the effect of naturally occurring organic matter (NOM) such as humic and fulvic acids (HA/FA), which may impact the efficiency of UV/Iodide photoreduction, is poorly understood.

View Article and Find Full Text PDF

N-nitrosodimethylamine (NDMA) has aroused extensive concern as a disinfection byproduct due to its high toxicity and elevated concentration levels in water sources. This study investigates the photoreductive decomposition of NDMA by UV/iodide process. The results showed that this process is an effective strategy for the treatment of NDMA with 99.

View Article and Find Full Text PDF

Perfluoroalkyl acids (PFAAs) have been found to be ubiquitously disseminated in the environment due to their widespread use in recent decades. In this study, the occurrence and spatiotemporal distribution of PFAAs in the surface water of Huangpu River, Shanghai, China were investigated from 2012 to 2014. The total concentration of 14 PFAAs (ΣPFAAs) ranged from 39.

View Article and Find Full Text PDF