Strontium doped Fe-based porous carbon for highly efficient electrocatalytic ORR and MOR reactions.

The catalytic activity improvement of Fe-based active sites derived from metal organic frameworks toward oxygen reduction reaction (ORR) and methanol oxidation reaction (MOR) remains a major challenge. In this study, the growth of strontium decorated 2-methylimidazole zinc salt (Sr/ZIF-8) is prepared as a carrier to vapor deposited iron formation Sr doped Fe-based nitrogen-doped carbon framework (named as Sr/FeNC). After high-temperature pyrolysis and vapor deposition, strontium carbonate nanocrystals are evenly dispersed on the shrunk dodecahedron carbon frame and multitudinous Fe-based active catalytic sites are embedded in carbon skeleton.

Cerium oxide boosted CoFe-N codoped carbon nanotubes with abundant oxygen-vacancies toward efficient oxygen reduction and methanol oxidation reaction.

In this study, we designed a novel strategy that utilizes N-doped carbon nanotubes as the chemical bond supporter to stabilize ultrafine CoFe alloy and introduces secondary CeO active sites into the hybrid, resulting in the formation of CeO/CoFe-NCNTs heterostructures with exceptional bifunctional electrocatalytic capabilities. To be specific, solution dispersion and high-temperature calcination methods were employed to create the CoFe-NCNTs active sites through the introduction of ethylenediamine into the network interstitials of Co-EDTA and Fe-EDTA. The CeO/CoFe-NCNTs hybrid not only promotes oxygen absorption and conversion of intermediates, but also accelerates charge transfer capability, thus enhancing oxygen reduction reaction (ORR) performance, while simultaneously inducing boosted the methanol oxidation reaction (MOR) activity.

Synergistic catalytic enhancement of metal-organic framework derived nanoarchitectures decorated on graphene as a high-efficiency bifunctional electrocatalyst for methanol oxidation and oxygen reduction.

Designing highly efficient, long-lasting, and cost-effective cathodic and anodic functional materials as a bifunctional electrocatalyst is essential for overcoming the bottleneck in fuel cell development. Herein, a novel two-step synthesis strategy is developed to synthesize metal-organic framework (MOF) derived nitrogen-doped carbon (NC) with improved spatial isolation and a higher loading amount of cobalt (Co) and nickel carbide (NiC) nanocrystal decorated on graphene (denoted as Co@NC-NiC/G). Benefiting from multiple active sites of high N-doping level, uniform dispersion of Co and NiC nanocrystals, and a large active area of graphene, the Co@NC-NiC/G hybrids exhibit excellent methanol oxidation reaction (MOR) and oxygen reduction reaction (ORR) efficiency in an alkaline environment.

Platinum quantum dots enhance electrocatalytic activity of bamboo-like nitrogen doped carbon nanotubes embedding Co-MnO nanoparticles for methanol/ethanol oxidation.

Interaction of multi-active components can effectively maximize the overall catalytic ability of alcohol fuel cells. Herein, the self-assembled nitrogen doped carbon nanotubes (NCNTs) containing Co-MnO composite (Co-MnO/NCNTs) are successfully synthesized using dihydrodiamine as carbon and nitrogen source through one-step synthesis. In order to further improve the catalytic activity of Co-MnO/NCNTs for alcohol oxidation, small amounts of platinum quantum dots are uniformly loaded on Co-MnO/NCNTs formation of quaternary hybrid (named Pt/Co-MnO/NCNTs) during microwave reduction stage.

Biocompatible G-Quadruplex/BODIPY assembly for cancer cell imaging and the attenuation of mitochondria.

The G-quadruplex aptamer is a high-order structure formed by folding of guanine-rich DNA or RNA. The recognition and assembly of G-quadruplex and compounds are important to find biocompatible drugs. Herein, triphenylamine conjugated 4, 4-difluoro-4-bora-3a, 4a-diaza-s-indacene (BODIPY) compound (BPTPA) was synthesized, and the interaction of BPTPA with G4 DNA was studied.