Cell-penetrating peptides noncovalently modified red phosphorescent nanoparticles for high-efficiency imaging.

The application of long-lived phosphorescence probes in time-resolved luminescence imaging is limited by their low quantum yield in aqueous solutions. However, sensitization of thermally activated delayed fluorescence (TADF) materials can compensate for this limitation while addressing the issue of insufficient proportion of their own long lifetime. In this study, we utilized the characteristics of phosphorescence and TADF materials simultaneously by doping the receptor iridium complex PMD-Ir into the donor TADF polymer PCzDP-20 through donor-receptor doping method, and successfully prepared highly efficient red phosphorescent nanoparticles.

2,6-Azulene-based Homopolymers: Design, Synthesis, and Application in Proton Exchange Membrane Fuel Cells.

Azulene-based homopolymers are of great interest from the point view of chemistry and material science. Herein, by means of Friedel-Crafts acylation to introduce solubilizing chains on the 1-position of azulene, we designed and synthesized two examples of 2,6-azulene-based homopolymers and . The arrangement of 2,6-azulene units is irregular for , while has head-to-head/tail-to-tail arranged 2,6-azulene units.