Heavy metal spatial distribution, source analysis, and ecological risks in the central hilly area of Hainan Island, China: results from a high-density soil survey.

The presence of heavy metals in soil has gained considerable attention due to their potential risks to ecosystems and human health. In this study, a thorough soil investigation was performed in the hilly region of central Hainan, which was formerly regarded as an area with the highest ecological environmental quality. A total of 7094 soil samples were systematically collected with high density over a large area.

Petrogenesis of the granitoids related to skarn-type mineralization in the Nyainqentanglha Metallogenic Belt, Tibet.

The Nyainqentanglha Metallogenic Belt (NMB) is an economically important lead-zinc ore province located in the Central and Southern Lhasa subterrane, Tibet. The NMB consists mainly of skarn-type lead-zinc polymetallic deposits that form at the contact between Late Cretaceous-Eocene intrusive rocks and carbonatite/volcanic-sedimentary strata. These deposits are generally considered to be related to S-type granites formed by the Indo-Asian continental collision.

Differentiating environmental scenarios to establish geochemical baseline values for heavy metals in soil: A case study of Hainan Island, China.

Soil heavy metal distributions exhibit regional heterogeneity due to the complex characteristics of parent materials and soil formation processes, emphasizing the need for appropriate regional standards prior to assessing soil risks. This study focuses on Hainan Island and employs the Multi-purpose Regional Geochemical Survey dataset to establish heavy metal geochemical baseline and background values for soil using an iterative method. Geographical detector analysis reveals that parent materials are the primary factor influencing heavy metal distribution, followed by soil types and land use.

Contamination and source of metals in surface sediments from the Nandu River of Hainan Island, China.

Concentrations of eight metals, organic carbon (Corg), and eight oxides were measured in 33 river sediment samples from the Nandu River. Sediment quality guidelines (SQGs) showed no severe pollution at all stations. However, according to the geo-accumulation index (Igeo), enrichment factor (EF), and potential ecological risk index (EI and RI), As and Cd were the primary pollutants in the survey area and caused low to moderate potential ecological risk.

Heavy metal pollution in agricultural soils of a typical volcanic area: Risk assessment and source appointment.

Heavy metals are naturally occurring elements with high natural background levels in the volcanic area. Therefore, it is necessary to conduct a risk assessment and identify potential sources of heavy metals. In this study, 4488 soil samples (0-20 cm) were collected in Chengmai County, a typical volcanic area in Hainan Province, and analyzed for eight heavy metals and major oxides.

Electricity generation, salinity, COD removal and anodic biofilm microbial community vary with different anode CODs in a microbial desalination cell for high-salinity mustard tuber wastewater treatment.

A three-chamber microbial desalination cell (MDC) was constructed for high-salinity mustard tuber wastewater (MTWW) treatment. The effect of anode COD on electricity generation, salinity, COD removal and the anodic biofilm microbial community in MDC for the MTWW treatment was investigated. The results showed that electricity generation was better when the anode COD was 900 mg L when it was 400 or 1400 mg L.

Removal of Microcystis aeruginosa by ultrasound: Inactivation mechanism and release of algal organic matter.

The efficacy of ultrasonic irradiation for removal of Microcystis aeruginosa and release of algal organic matter (AOM) was investigated under different ultrasound conditions, including ultrasonic frequency, power density, and time. Laboratory results suggested that the ultrasonic efficiency and the release of AOM were influenced by frequency, power density, and time. The mechanism of AOM algae removal by ultrasound was systematically explored.

A chemical defence against phage infection.

The arms race between bacteria and the phages that infect them drives the continual evolution of diverse anti-phage defences. Previously described anti-phage systems have highly varied defence mechanisms; however, all mechanisms rely on protein components to mediate defence. Here we report a chemical anti-phage defence system that is widespread in Streptomyces.

Proton Probability Distribution in the O···H···O Low-Barrier Hydrogen Bond: A Combined Solid-State NMR and Quantum Chemical Computational Study of Dibenzoylmethane and Curcumin.

We report a combined solid-state (H, H, C, O) NMR and plane-wave density functional theory (DFT) computational study of the O···H···O low-barrier hydrogen bonds (LBHBs) in two 1,3-diketone compounds: dibenzoylmethane (1) and curcumin (2). In the solid state, both 1 and 2 exist in the cis-keto-enol tautomeric form, each exhibiting an intramolecular LBHB with a short O···O distance (2.435 Å in 1 and 2.