Organophosphate esters in vehicle interior dust from Chinese urban areas: What are the influencing factors of the occurrence?

Organophosphate esters (OPEs) are a class of semi-volatile organic compounds frequently used to various products as flame retardants and plasticizers. As emerging pollutants, OPEs have attracted significant attention due to their potential impacts on human health and ecosystems. This study investigated the occurrence of OPEs in vehicle interior dust across 36 cities in China.

[Occurrence Characteristics and Health Risk Assessment of Organophosphate Esters in Tap Water of Shanghai].

To explore the occurrence characteristics and health risk levels of the new pollutants organophosphate esters （OPEs） in tap water in Shanghai, based on the water supply areas of the Qingcaosha Reservoir, Chenhang Reservoir, Dongfeng Xisha Reservoir, and Upstream Huangpu River water sources, a total of 52 large shopping malls in Shanghai were selected as tap water sampling sites. Solid phase extraction and gas chromatography-triple quadrupole mass spectrometry were used to determine eight types of OPEs in tap water from shopping malls, including three types of chlorinated OPEs, two types of alkyl OPEs, and three types of aryl OPEs. On this basis, the health risk assessment of the substances with high detection frequency and concentration was carried out.

A New Diffusion Strategy Using an Epidemic Spreading Model for Encryption.

The diffusion phenomenon that exhibits intrinsic similarities is pervasive in cryptography and natural systems, evident in liquid diffusion, epidemic spread, animal migration, and encryption techniques. In cryptography, bytes are systematically diffused in a sequential manner to encrypt the value of each byte in the plaintext in a linear fashion. In contrast, within an epidemic spreading model, the diffusion process can be represented within a complex, multilayered network, encompassing layers such as familial and social transmission dynamics.

Highly Selective Recovery of Gold by In Situ Magnetic Field-Assisted Fe/Co-MOF@PDA/NdFeB Double Network Gel.

There are enormous economic benefits to conveniently increasing the selective recovery capacity of gold. Fe/Co-MOF@PDA/NdFeB double-network organogel (Fe/Co-MOF@PDA NH) is synthesized by aggregation assembly strategy. The package of PDA provides a large number of nitrogen-containing functional groups that can serve as adsorption sites for gold ions, resulting in a 21.

Effect of nitrogen oxides and sulfur oxides to triphenyl phosphate degradation and cytotoxicity on surface of different transition metal salts.

Nitrogen oxides and sulfur oxides, as the dominant toxic gases in the atmosphere, can induce severe human health problems under the composite pollutant conditions. Currently the effect of nitrogen or sulfur oxides in atmospheric environment to the degradation and cytotoxicity of triphenyl phosphate (TPhP) on atmospheric particle surfaces still remain poorly understood. Hence, laboratory simulation methods were used in this study to investigate the effect and related mechanism.

Degradation, transformation and cytotoxicity of triphenyl phosphate on surface of different transition metal salts in atmospheric environment.

Triphenyl phosphate (TPhP) and transition metal elements have been ubiquitously detected in the atmosphere, which can participate in atmospheric chemical reactions and induce damage to human health. Currently the understanding of TPhP degradation, transformation and cytotoxicity on atmospheric particles surface are still limited. Therefore, this study used laboratory simulation methods to investigate the influence of irradiation time, transition metal salts, relative humidity (RH) to TPhP degradation, transformation and relative cytotoxicity.

High Systemic Inflammatory Protein Index Is Associated with Clinically Ineffective Reperfusion in Acute Anterior Circulation Ischemic Stroke Patients Undergoing Endovascular Treatment.

Nearly half of the patients undergoing endovascular treatment (EVT) do not have favorable outcomes despite successful recanalization of the occluded artery, which is also known as clinically ineffective reperfusion. We proposed a novel index-the systemic inflammatory protein index (SIPI), based on albumin, globulin, and C-reaction protein (CRP). We aimed to evaluate the relationship between inflammatory biomarkers at varying time points and the 90-day functional outcomes and investigate inflammatory biomarkers' dynamic changes during hospitalization in acute ischemic stroke (AIS) patients of anterior circulation undergoing EVT.

Further Insight into Extractable (Organo)fluorine Mass Balance Analysis of Tap Water from Shanghai, China.

The ubiquitous occurrence of per- and polyfluoroalkyl substances (PFAS) and the detection of unexplained extractable organofluorine (EOF) in drinking water have raised growing concerns. A recent study reported the detection of inorganic fluorinated anions in German river systems, and therefore, in some samples, EOF may include some inorganic fluorinated anions. Thus, it might be more appropriate to use the term "extractable fluorine (EF) analysis" instead of the term EOF analysis.

Evaluation of the oral bioaccessibility of legacy and emerging brominated flame retardants in indoor dust.

Indoor dust is the main source of human exposure to brominated flame retardants (BFRs). In this study, in vitro colon-extended physiologically-based extraction test (CE-PBET) with Tenax as a sorptive sink was applied to evaluate the oral bioaccessibility of twenty-two polybrominated diphenyl ethers (PBDEs) and seven novel BFRs (NBFRs) via indoor dust ingestion. The mean bioaccessibilities of two NBFRs pentabromotoluene (PBT) and 1,2-Bis(2,4,6-tribromophenoxy) ethane (BTBPE) were first proposed, reaching 36.

FeO quantum dots mediated P-g-CN/BiOI as an efficient and recyclable Z-scheme photo-Fenton catalyst for tetracycline degradation and bacterial inactivation.

Photo-Fenton technology integrated by photocatalysis and Fenton reaction is a favorable strategy for water remediation. Nevertheless, the development of visible-light-assisted efficient and recyclable photo-Fenton catalysts still faces challenges. This study successfully constructed a novel separable Z-scheme P-g-CN/FeOQDs/BiOI (PCN/FOQDs/BOI) heterojunction via in-situ deposition method.

An Optimized Convolutional Neural Network for the 3D Point-Cloud Compression.

Due to the tremendous volume taken by the 3D point-cloud models, knowing how to achieve the balance between a high compression ratio, a low distortion rate, and computing cost in point-cloud compression is a significant issue in the field of virtual reality (VR). Convolutional neural networks have been used in numerous point-cloud compression research approaches during the past few years in an effort to progress the research state. In this work, we have evaluated the effects of different network parameters, including neural network depth, stride, and activation function on point-cloud compression, resulting in an optimized convolutional neural network for compression.

Geometry Sampling-Based Adaption to DCGAN for 3D Face Generation.

Despite progress in the past decades, 3D shape acquisition techniques are still a threshold for various 3D face-based applications and have therefore attracted extensive research. Moreover, advanced 2D data generation models based on deep networks may not be directly applicable to 3D objects because of the different dimensionality of 2D and 3D data. In this work, we propose two novel sampling methods to represent 3D faces as matrix-like structured data that can better fit deep networks, namely (1) a geometric sampling method for the structured representation of 3D faces based on the intersection of iso-geodesic curves and radial curves, and (2) a depth-like map sampling method using the average depth of grid cells on the front surface.

Double-Color-Image Compression-Encryption Algorithm Based on Quaternion Multiple Parameter DFrAT and Feature Fusion with Preferable Restoration Quality.

To achieve multiple color images encryption, a secure double-color-image encryption algorithm is designed based on the quaternion multiple parameter discrete fractional angular transform (QMPDFrAT), a nonlinear operation and a plaintext-related joint permutation-diffusion mechanism. QMPDFrAT is first defined and then applied to encrypt multiple color images. In the designed algorithm, the low-frequency and high-frequency sub-bands of the three color components of each plaintext image are obtained by two-dimensional discrete wavelet transform.

TiM-Net: Transformer in M-Net for Retinal Vessel Segmentation.

retinal image is a crucial window for the clinical observation of cardiovascular, cerebrovascular, or other correlated diseases. Retinal vessel segmentation is of great benefit to the clinical diagnosis. Recently, the convolutional neural network (CNN) has become a dominant method in the retinal vessel segmentation field, especially the U-shaped CNN models.

A pilot study on extractable organofluorine and per- and polyfluoroalkyl substances (PFAS) in water from drinking water treatment plants around Taihu Lake, China: what is missed by target PFAS analysis?

Per- and polyfluoroalkyl substances (PFAS) have raised concerns due to their worldwide occurrence and adverse effects on both the environment and humans as well as posing challenges for monitoring. Further collection of information is required for a better understanding of their occurrence and the unknown fractions of the extractable organofluorine (EOF) not explained by commonly monitored target PFAS. In this study, eight pairs of raw and treated water were collected from drinking water treatment plants (DWTPs) around Taihu Lake in China and analyzed for EOF and 34 target PFAS.

Efficient organics heterogeneous degradation by spinel CuFeO supported porous carbon nitride catalyst: Multiple electron transfer pathways for reactive oxygen species generation.

Facilitating reactive oxygen species (ROS) generation is an effective way to promote the heterogeneous catalytic efficiency for organics removal. However, the metal leaching in metal-based catalysts and the low activity of non-metallic materials restrict ROS production. In this work, the purpose was achieved by loading a small amount of spinel CuFeO onto porous carbon nitride substrate.

Alkyl organophosphate flame retardants (OPFRs) induce lung inflammation and aggravate OVA-simulated asthmatic response via the NF-кB signaling pathway.

Alkyl organophosphate flame retardants (OPFRs), tri-n-butyl phosphate (TnBP) and tris(2-butoxyethyl) phosphate (TBOEP), are ubiquitously detected in indoor and outdoor environments and their inhalation may result in lung damage. This study examined pulmonary toxicity after exposure to TnBP or TBOEP and investigated aggravation of inflammation and immunoreaction by TnBP in an ovalbumin (OVA)-induced mice model. Transcriptomics were used to further reveal the underlying mechanism.

Novel sphere-like copper bismuth oxide fabricated via ethylene glycol-introduced solvothermal method with improved adsorptive and photocatalytic performance in sulfamethazine removal.

In this research, ethylene glycol-introduced solvothermal method was employed to fabricate a novel sphere-like CuBiO material to improve the adsorptive and photocatalytic performance of conventional CuBiO. A series of characterization has been applied to investigate properties of the obtained CuBiO (CBO-EG3). Compared with conventional rod-like CuBiO (CBO), the synthesized sphere-like CBO-EG3 exhibited rough surface, larger specific surface area, and more effective separation of photo-generated carriers, which overcome main shortcomings of CuBiO.

A review of secondary organic aerosols formation focusing on organosulfates and organic nitrates.

Secondary organic aerosols (SOA) are crucial constitution of fine particulate matter (PM), which are mainly derived from photochemical oxidation products of primary organic matter and volatile organic compounds (VOCs), and can induce terrible impacts to human health, air quality and climate change. As we know, organosulfates (OSs) and organic nitrates (ON) are important contributors for SOA formation, which could be possibly produced through various pathways, resulting in extremely complex formation mechanism of SOA. Although plenty of research has been focused on the origins, spatial distribution and formation mechanisms of SOA, a comprehensive and systematic understanding of SOA formation in the atmosphere remains to be detailed explored, especially the most important OSs and ON dedications.

Operational assessment tool for forest carbon dynamics for the United States: a new spatially explicit approach linking the LUCAS and CBM-CFS3 models.

Background: Quantifying the carbon balance of forested ecosystems has been the subject of intense study involving the development of numerous methodological approaches. Forest inventories, processes-based biogeochemical models, and inversion methods have all been used to estimate the contribution of U.S.

Organophosphate flame retardants induce oxidative stress and Chop/Caspase 3-related apoptosis via Sod1/p53/Map3k6/Fkbp5 in NCI-1975 cells.

Organophosphate flame retardants (OPFRs) have been ubiquitously detected in dust and air which could cause damage to human health through inhalation. Currently the understanding of their adverse effects and potential mechanisms on the lung are still limited. In this study, human non-small cell lung cancer cell line NCI-H1975 was used to investigate the cytotoxicity, oxidative stress, cellular apoptosis of 9 typical OPFRs with concentrations varied from 0 to 200 μM, and their toxic mechanism associated with molecular structure was compared.