How different stress responses by male and female plants are influenced by interactions with rhizosphere microbes remains unclear. In this study, we employed poplar as a dioecious model plant and quantified biotic associations between microorganisms to explore the relationship between microbial associations and plant adaptation. We propose a health index (HI) to comprehensively characterize the physiological characteristics and adaptive capacity of plants under stress.
View Article and Find Full Text PDFNanomaterials (Basel)
November 2024
With the growing demand for personalized healthcare services, biomaterial-based triboelectric nanogenerators (BM-TENGs) have gained widespread attention due to their non-toxicity, biocompatibility, and biodegradability. This review systematically examines the working principles, material choices, biomimetic designs, and clinical application scenarios of BM-TENGs, with a focus on the use of natural biomaterials, biocomposites, hydrogels, and other materials in health diagnostics. Biomaterials show significant potential in enhancing TENG performance, improving device flexibility, and expanding application ranges, especially in early disease detection, health monitoring, and self-powered sensing devices.
View Article and Find Full Text PDFAll-inorganic perovskites prepared by substituting the organic cations (e.g. methylammonium (MA) and formamidinium (FA)) with inorganic cations (e.
View Article and Find Full Text PDFCurrently, triboelectric nanogenerators (TENGs) are drawing significant attention owing to their potential in harvesting wave and wind energy from environment as well as their capability for driving electrochemical water splitting for hydrogen fuel production. This review aims to summarize the recent progress of ocean wave and wind energy harvesting TENGs and TENG-driven electrochemical water splitting processes for hydrogen evolution reaction. For better understanding, this review begins from the fundamentals of TENG and electrochemical water splitting.
View Article and Find Full Text PDFJ Colloid Interface Sci
November 2024
To achieve high-performance Zn-air batteries (ZABs), the development of bifunctional air electrodes capable of efficiently mediating both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) is imperative. In this study, we present an N-doped carbon hollow nanorod encapsulating a semi-coherent Co-Ni/CoMoC heterojunction, tailored for reversible oxygen catalysis. This nanohybrid demonstrated an ORR half-wave potential of 0.
View Article and Find Full Text PDFIn advancing the transition of the energy sector toward heightened sustainability and environmental friendliness, biopolymers have emerged as key elements in the construction of triboelectric nanogenerators (TENGs) due to their renewable sources and excellent biodegradability. The development of these TENG devices is of significant importance to the next generation of renewable and sustainable energy technologies based on carbon-neutral materials. This paper introduces the working principles, material sources, and wide-ranging applications of biopolymer-based triboelectric nanogenerators (BP-TENGs).
View Article and Find Full Text PDFNowadays, magnetic materials are also drawing considerable attention in the development of innovative energy converters such as triboelectric nanogenerators (TENGs), where the introduction of magnetic materials at the triboelectric interface not only significantly enhances the energy harvesting efficiency but also promotes TENG entry into the era of intelligence and multifunction. In this review, we begin from the basic operating principle of TENGs and then summarize the recent progress in applications of magnetic materials in the design of TENG magnetic materials by categorizing them into soft ferrites and amorphous and nanocrystalline alloys. While highlighting key role of magnetic materials in and future opportunities for improving their performance in energy conversion, we also discuss the most promising choices available today and describe emerging approaches to create even better magnetic TENGs and TENG-based sensors as far as intelligence and multifunctionality are concerned.
View Article and Find Full Text PDFSimultaneously optimizing the d-band center of the catalyst and the mass/charge transport processes during the oxygen catalytic reaction is an essential but arduous task in the pursuit of creating effective and long-lasting bifunctional oxygen catalysts. In this study, a Fe-Co/MoC@N-doped carbon macroporous nanoframe was successfully synthesized a facile "conformal coating and coordination capture" pyrolysis strategy. As expected, the resulting heterogeneous electrocatalyst exhibited excellent reversible oxygen electrocatalytic performance in an alkaline medium, as demonstrated by the small potential gap of 0.
View Article and Find Full Text PDFThe fabrication of a remarkably efficient iron-metal-based pair-site, constrained within carbon support, presents a significant and intricate undertaking, primarily attributable to the propensity of proximate metallic entities to amalgamate into the alloy state. In response to this challenge, a spatial segregation approach was conceptualized, aiming to synthesize an N/S co-doped carbon nanobox hosting an asymmetrically coupled Fe-Co pair-site. This engineered nanostructure manifested remarkable electrocatalytic properties, notably featuring a superb half-wave potential of 0.
View Article and Find Full Text PDFThe advancement of bifunctional oxygen catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is imperative yet challenging for the optimization of Zn-air batteries. In this study, we reported the successful incorporation of a novel Mott-Schottky catalytic site within a MnO-FeCo heterojunction into an N-doping carbon nanobox, taking into consideration the effects of the intrinsic electric field and hollow/porous support carriers for electrocatalyst design. As expected, the resulting heterogeneous catalyst exhibited an encouraging half-wave potential of 0.
View Article and Find Full Text PDFTriboelectric nanogenerators (TENGs) have revolutionized energy harvesting and active sensing, holding tremendous potential in personalized healthcare, sustainable diagnoses, and green energy applications. In these scenarios, conductive polymers play a vital role in enhancing the performance of both TENG and TENG-based biosensors, enabling the development of flexible, wearable, and highly sensitive diagnostic devices. This review summarizes the impact of conductive polymers on TENG-based sensors, focusing on their contributions to triboelectric properties, sensitivity, detection limits, and wearability.
View Article and Find Full Text PDFTriboelectric nanogenerators (TENGs) have garnered considerable interest as a promising technology for energy harvesting and stimulus sensing. While TENGs facilitate the generation of electricity from micro-motions, the modular design of TENG-based modular sensing systems (TMSs) also offers significant potential for powering biosensors and other medical devices, thus reducing dependence on external power sources and enabling biological processes to be monitored in real time. Moreover, TENGs can be customised and personalized to address individual patient needs while ensuring biocompatibility and safety, ultimately enhancing the efficiency and security of diagnosis and treatment.
View Article and Find Full Text PDFBiosensors (Basel)
January 2023
Piezoelectric nanogenerators (PENGs) not only are able to harvest mechanical energy from the ambient environment or body and convert mechanical signals into electricity but can also inform us about pathophysiological changes and communicate this information using electrical signals, thus acting as medical sensors to provide personalized medical solutions to patients. In this review, we aim to present the latest advances in PENG-based non-invasive sensors for clinical diagnosis and medical treatment. While we begin with the basic principles of PENGs and their applications in energy harvesting, this review focuses on the medical sensing applications of PENGs, including detection mechanisms, material selection, and adaptive design, which are oriented toward disease diagnosis.
View Article and Find Full Text PDFLiver-related disease caused by alcohol is a frequent disorder of the hepatic tract. Heavy consumption of alcohol in a short period causes oxidative damage to the liver. Sea cucumber is abundant in nutrients and its various extracts have been studied for antioxidant properties.
View Article and Find Full Text PDFLead halide perovskite CsPbBr quantum dots (QDs) possess several desirable features which enable them to be promising candidates for photocatalysis. However, the instability caused by their inherent liquid-like ionic properties hampers their further development. Herein, this work employs the surficial molecular modification strategy and a multi-dimensional structure design to ease the instability issue.
View Article and Find Full Text PDFSelective removal of carbonyl sulfide (COS) and hydrogen sulfide (HS) is the key step for natural gas desulfurization due to the highly toxic and corrosive features of these gaseous sulfides, and efficient and stable desulfurizers are urgently needed in the industry. Herein, we report a class of nitrogen-functionalized, hierarchically lamellar carbon frameworks (N-HLCF-xs), which are obtained from the structural transformation of Zn zeolitic imidazolate frameworks via controllable carbonization. The N-HLCF-xs possess the desirable characteristics of large Brunauer-Emmett-Teller surface areas (645-923 m/g), combined primary three-dimensional microporosity and secondary two-dimensional lamellar microstructure, and high density of nitrogen base sites with enhanced pyridine ratio (17.
View Article and Find Full Text PDFPhyllosphere bacteria are an important component of environmental microbial communities and are closely related to plant health and ecosystem stability. However, the relationships between the inhabitation and assembly of phyllosphere bacteria and leaf microtopography are still obscure. In this study, the phyllosphere bacterial communities and leaf microtopographic features (vein density, stomatal length, and density) of eleven tree species were fully examined.
View Article and Find Full Text PDFUnderstanding the succession patterns of microbial community along root growth provides deep insights into interaction between fine roots and microbes. In the study, we investigated this issue using fine roots from poplar trees and grouped these fine roots into three growth stages: newborn white roots (WR), mature yellow roots (YR) and aging brown roots (BR). Root surface traits were observed under a scanning electron microscopy (SEM).
View Article and Find Full Text PDFColloids Surf B Biointerfaces
December 2019
The electrochemical properties of CoCrMo alloy immersed in different artificial saliva with or without Ca and albumin were studied by open circuit potential (OCP), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PP), and meanwhile the microstructures features, phase identification and chemical composition of the alloy were analyzed by SEM, EDS, XRD and RA-IR to further understand the electrochemical behavior of the alloy. The results indicated that the self-passivation behavior of the alloy occurred universally and was obviously distinct with each other in different acidic artificial saliva. No phase transformation was observed and the oxide layer and corrosion products exhibited amorphous nature.
View Article and Find Full Text PDFFinite element models are increasingly important in understanding head injury mechanisms and designing new injury prevention equipment. Although boundary conditions strongly influence model responses, only limited quantitative data are available. While experimental studies revealed some motion between brain and skull, little data exists regarding the base of the skull.
View Article and Find Full Text PDFThe objective of this study was to define the constitutive response of brainstem undergoing finite shear deformation. Brainstem was characterized as a transversely isotropic viscoelastic material and the material model was formulated for numerical implementation. Model parameters were fit to shear data obtained in porcine brainstem specimens undergoing finite shear deformation in three directions: parallel, perpendicular, and cross sectional to axonal fiber orientation and determined using a combined approach of finite element analysis (FEA) and a genetic algorithm (GA) optimizing method.
View Article and Find Full Text PDFThe objective of this study was to utilize tissue deformation thresholds associated with acute axonal injury in the immature brain to predict the duration of unconsciousness. Ten anesthetized 3- to 5-day-old piglets were subjected to nonimpact axial rotations (110-260 rad/s) producing graded injury, with periods of unconsciousness from 0 to 80 min. Coronal sections of the perfusion-fixed brain were immunostained with neurofilament antibody (NF-68) and examined microscopically to identify regions of swollen axons and terminal retraction balls.
View Article and Find Full Text PDFClinical and biomechanical evidence indicates that mechanisms and pathology of head injury in infants and young children may be different from those in adults. Biomechanical computer-based modeling, which can be used to provide insight into the thresholds for traumatic tissue injury, requires data on material properties of the brain, skull, and sutures that are specific for the pediatric population. In this study, brain material properties were determined for rats at postnatal days (PND) 13, 17, 43, and 90, and skull/suture composite (braincase) properties were determined at PND 13, 17, and 43.
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