A series of novel [Ir(tpy)(btp)Cl] complexes (Ir1-Ir4) have been reported to show excellent performance as photosensitizers. The introduction of electron-withdrawing groups increases visible light absorption and the lifetime of triplet states. To improve the photophysical properties, we theoretically design Ir5-Ir9 with electron-withdrawing groups (Cl, F, COOH, CN and NO).
View Article and Find Full Text PDFThe present study investigates the standard model of [1,2]-fluorine migration and that triggered by the rearrangement of cyclopropyl-substituted fluoroepoxides. The [1,2]-fluorine migration reaction proceeds a synchronous concerted, tight-ion-pair mechanism. When coupled with other reaction coordinates, the whole reaction follows an asynchronous mechanism, while the [1,2]-fluorince migration unit still retains its tight-ion-pair feature and the reaction coordinates of two C-F distances vary synchronously.
View Article and Find Full Text PDFThe first application of an imidazole MOF, the 2D Co(II)- imidazole framework, {[Co(TIB) (H O) ]SO } (TIB stands for 1,3,5-tris(1-imidazolyl) benzene) (CoTIB) in photocatalytic CO reduction was carried out, and compared with that of ZIF-67. The CO /CoTIB (1.0 mg)/Ru(bpy) Cl (bpy=2,2'-bipyridine) (11.
View Article and Find Full Text PDFTwo zinc-boron clusters (ZnBeB(CN) and ZnBeB(CN)) reported in a theoretical study by P. Jena and co-workers are reinvestigated using quantum chemistry calculations. The results prove that the zinc atoms in these two clusters retain a normal oxidation state of +2, overturning the conclusion reached in the previous study that a +3 oxidation state is present.
View Article and Find Full Text PDFWe report a paper-based chemosensor array device (PCSAD) for the quantitative detection of oxyanions including the herbicide glyphosate (GlyP) in aqueous media. The mechanism of the oxyanion detection relies on a coordination-binding-based sensor array. In this study, the competitive coordination binding among Zn , four catechol dyes, and seven oxyanions caused noticeable colour changes.
View Article and Find Full Text PDFSimple, rapid, and accurate detection methods for saccharides are potentially applicable to various fields such as clinical and food chemistry. However, the practical applications of on-site analytical methods are still limited. To this end, herein, we propose a 96-well microtiter plate made of paper as a paper-based chemosensor array device (PCSAD) for the simultaneous classification of 12 saccharides and the quantification of fructose and glucose among 12 saccharides.
View Article and Find Full Text PDFInvited for the cover of this issue is the group of Tsuyoshi Minami at the University Tokyo. The image illustrates that despite being fabricated with the same polythiophene material, a water-gated organic thin-film transistor is a more sensitive device than a fluorescence sensor chip. Read the full text of the article at 10.
View Article and Find Full Text PDFThis work reports the design of a highly sensitive solid-state sensor device based on a water-gated organic thin-film transistor (WG-OTFT) for the selective detection of herbicide glyphosate (GlyP) in water. A competitive assay among carboxylate-functionalized polythiophene, Cu , and GlyP was employed as a sensing mechanism. Molecular recognition phenomena and electrical double layer (EDL) (at the polymer/water interface) originated from the field-effect worked cooperatively to amplify the sensitivity for GlyP.
View Article and Find Full Text PDFAn artificial tongue that detects astringent components for a comprehensive evaluation of taste has not been established to date. Herein, we first propose fluorescent polythiophene (PT) derivatives (S1-S3) modified with 3-pyridinium boronic acid as supramolecular chemosensors for wine components including astringent procyanidin C1. After numerous attempts for the synthetic conditions, more than 95 mol % of the PT unit was modified with the pyridinium boronic acid moiety.
View Article and Find Full Text PDFA novel fluorescence chemosensor array composed of pyrenylboronic acid-based probes for multi- anion detection has been developed. The pyrenylboronic acid derivatives showed fluorescence quenching or enhancement due to photoinduced electron transfer originating from anion binding. The recognition ability was assessed by fluorescence titrations and electrospray ionization mass spectrometry.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2020
A porous polyimide (PI) membrane is successfully prepared via nonsolvent-induced phase separation with two porogens: dibutyl phthalate and glycerin. The as-prepared uniform porous PI membrane shows excellent separator properties for lithium-ion batteries (LIBs). Compared with the commercial polyethylene (PE) separator, the PI separator exhibits significant thermal stability, better ionic conductivity, and wettability both in carbonate and ether electrolytes for LIBs.
View Article and Find Full Text PDFAlthough the determination of oxyanions due to correlation with metabolic processes and diseases is in high demand, most of the developed methods are suffering from a shortage of a capability of on-site analysis, sensitivity, and user-friendliness. This paper introduces the first colorimetric chemosensor array targeting various anions including glyphosate. The proposed sensor benefits from some notable features such as utilizing only commercially available reagents, recognizing similarly structured compounds by biomaterial-free sensors, and providing a fingerprint-like response originating from pattern recognition.
View Article and Find Full Text PDFHerein, a very simple colorimetric chemosensor array is reported for saccharides (-glucose, -fructose, -xylose, -galactose, -mannose, -rhamnose, and -acetyl--gluosamine). While various types of chemosensors for saccharides have been investigated extensively to-this-date, tremendous additional efforts are still required on a regular basis for the syntheses of new chemosensors. Complicated syntheses would be a bottleneck, given that artificial receptor-based chemosensing systems are not so popular in comparison to biomaterial-based (e.
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