Operando Optical Imaging of Cathode Swelling Process Inside Lithium Primary Batteries: Comparative Studies between Different Structured CF.

As a crucial cathode material with ultrahigh theoretical capacity (865 mAh/g) and energy density (>2100 Wh/kg), fluorinated carbon (CF) is promising for lithium primary batteries. However, the operating performance of CF cathode is hindered by nonuniform volume expansion during discharging. To investigate this, we used operando confocal microscopy to visualize the thickness evolution of two different CF cathodes and quantified their swelling ratios as a function of the discharge depth.

Boosting the Electrochemical Performance of Primary and Secondary Lithium Batteries with Mn-Doped All-Fluoride Cathodes.

Transition metal fluorides are potentially high specific energy cathode materials of next-generation lithium batteries, and strategies to address their low conductivity typically involve a large amount of carbon coating, which reduces the specific energy of the electrode. In this study, MnFeF@CF was generated by the all-fluoride strategy, converting most of the carbon in MnFeF@C into electrochemical active CF through a controllable NF gas phase fluorination method, while still retaining a tightly bound graphite layer to provide initial conductivity, which greatly improved the energy density of the composite. This synergistic effect of nonfluorinated residual carbon (∼11%) and Mn doping ensures the electrochemical kinetics of the composite.

Solvation Structure Tuning Induces LiF/Li N-Rich CEI and SEI Interfaces for Superior Li/CF Batteries.

The electrode/electrolyte interfaces play an important role in the electrochemical reaction kinetics to alleviate the severe polarization and voltage hysteresis in lithium primary batteries. Herein, C F N is proposed as an electrolyte additive to tune the characteristics of the electrode/electrolyte interfaces. The Li/CF primary battery with C F N additive exhibits an excellent discharge-specific capacity of 981.

Nanostructured Iron Fluoride Derived from Fe-Based Metal-Organic Framework for Lithium Ion Battery Cathodes.

A comprehensive strategy for the morphological control of octahedral and spindle Fe-based metal-organic frameworks (Fe-MOFs) via microwave-assisted adjustment is proposed in this research. Afterward, in situ copyrolysis under N atmosphere contributes to the fabrication of two shape-maintained FeF·0.33HO nanostructures (named O-FeF·0.

Copper nanowires and copper foam multifunctional bridges in zeolitic imidazolate framework-derived anode material for superior lithium storage.

Herein, a synthetic strategy for growing trimetallic zeolitic imidazolate framework (ZIF) polyhedrons on copper foam (CF) and interweaving with copper nanowires (CNWs) is proposed. Subsequently, in situ annealing under N atmosphere leads to the formation of multi-doped CNWs/CuZnCoO-ZnO/CF (CNWs/CZCOZ/CF). The unique structural characteristics of CNWs/CZCOZ/CF allow it to be directly assembled as a working electrode, without additional conductive additives or binders.