Photodeformable Azobenzene-Containing Polyimide with Flexible Linkers and Molecular Alignment.

Azobenzene-containing polyimides (azo-PIs) as photodeformable materials have attracted scientific attention in view of combining photoresponse and high performance (such as excellent mechanical and thermal properties). In the previously reported photodeformation of azo-PIs, polarized blue-green light was utilized to produce concerted motion of azobenzene moieties based on the mechanism of photoinduced reorientation. Herein, we explored a designed azo-PI undergoing photodeformation upon unpolarized light irradiation.

Colorless Semi-Alicyclic Copolyimides with High Thermal Stability and Solubility.

A series of colorless copolyimide films with high thermal stability and good solubility are synthesized from (trifluoromethyl)biphenyl-4,4'-diamine (TFMB) with different 1,2,4,5-cyclohexanetetracarboxylic dianhydride (HPMDA) to 2,2-bis(3,4-dicarboxyphenyl)-hexafluoropropane (6FDA) dianhydride mole ratios through one-pot solution polycondensation. These copolyimide films exhibit excellent optical transparency ( > 90% and ~305-333 nm) with a thickness of 15 μm and good solubility in most organic solvents. The excellent optical properties are mainly attributed to the low inter- and intra-molecular charge transfer interactions due to the alicyclic structure and the strong electronegative CF groups.

Transparent, High Glass-Transition Temperature, Shape Memory Hybrid Polyimides Based on Polyhedral Oligomeric Silsesquioxane.

Optically transparent polyimides with excellent thermal stability and shape memory effect have potential applications in optoelectronic devices and aerospace industries. A series of optically transparent shape memory polyimide hybrid films are synthesized from 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA) and 2,2'-bis-(trifluoromethyl)biphenyl-4,4'-diamine (TFMB) with various polyhedral oligomeric silsesquioxane (POSS) contents and then subjected to thermal imidization. The hybrid films show good optical transparency (>80% at 400 nm and >95% at 500 nm) with cutoff wavelengths ranging from 318 to 336 nm.