Surface Chemistry Modulation of BaGdLaCoO As Active Air Electrode for Solid Oxide Cells.

Modulation of the surface chemistry of air electrodes makes it possible to significantly improve the electrocatalytic performance of solid oxide cells (SOCs). Here, the surface chemistry of BaGdLaCoO (BGLC) double perovskite is modulated by treatment in an acidic citric acid solution. The treatment leads to corrosion on the surface of BGLC particles, and the effect is dependent on the acidity of the solution.

Electrochemically Assisted Construction of a LaNiO@Pt Core-Shell Structure for Enhancing the Performance and Durability of LaNiO Cathodes.

Ruddlesden-Popper oxide LaNiO (LNO) has a high ionic conductivity and good thermal match with the electrolyte of solid oxide fuel cells (SOFCs); however, LNO suffers from performance decay owing to the La surface segregation under the operation conditions of SOFCs. Herein, we report an in situ electrochemical decoration strategy to improve the electrocatalytic activity and durability of LNO cathodes. We show that the electrochemical polarization leads to in situ construction of the LNO@Pt core-shell structure, significantly suppressing the detrimental effect of La surface segregation on the LNO cathode.

Facile Construction of Nanostructured Cermet Anodes with Strong Metal-Oxide Interaction for Efficient and Durable Solid Oxide Fuel Cells.

Nanostructured anodes generate massive reaction sites to oxidize fuels in solid oxide fuel cells (SOFCs); however, the nonexistence of a practically viable approach for the construction of nanostructures and the retention of these nanostructures under the harsh operating conditions of SOFCs poses a significant challenge. Herein, a simple procedure is reported for the construction of a nanostructured Ni-Gd-doped CeO anode based on the direct assembly of pre-formed nanocomposite powder with strong metal-oxide interaction. The directly assembled anode forms heterointerfaces with the electrolyte owing to the electrochemical polarization current and exhibits excellent structural robustness against thermal ripening.

Facile Approach for Improving the Interfacial Adhesion of Nanofiber Air Electrodes of Reversible Solid Oxide Cells.

Nanofibers have great promise as a highly active air electrode for reversible solid oxide cells (ReSOCs); however, one thorny issue is how to adhesively stick nanofibers to electrolyte with no damage to the original morphology. Herein, PrBaCaCoO (PBCC) nanofibers are applied as an air electrode by a facile direct assembly approach that leads to the retention of most of the unique microstructure of nanofibers, and firm adhesion of the nanofiber electrode onto the electrolyte is achieved by applying electrochemical polarization. A single cell with the PBCC nanofiber air electrode exhibits excellent maximum power density (1.

Ultrafine, Dual-Phase, Cation-Deficient PrBaCaCoO Air Electrode for Efficient Solid Oxide Cells.

Nanostructured air electrodes play a crucial role in improving the electrocatalytic activity of oxygen reduction and evolution reactions in solid oxide cells (SOCs). Herein, we report the fabrication of a nanostructured BaCoO-decorated cation-deficient PrBaCaCoO (PBCC) air electrode via a combined modification and direct assembly approach. The modification approach endows the dual-phase air electrode with a large surface area and abundant oxygen vacancies.

Resistive Switching and the Local Electric Field in BiPrREFeMnO/CuFeO (RE = Sr, Dy) Bilayered Thin Films.

Bilayer BiPrREFeMnO/CuFeO (BPREFMO/CuFO, RE = Sr, Dy) thin films were prepared on FTO/glass substrates by the chemical solution deposition method. The structure transition does not appear after ion doping, which is confirmed by XRD and its refined results. The samples remain in the trigonal R3c:H structure in the BFO phase and in the tetragonal I41/amd structure in the CuFO phase.