Publications by authors named "Zhongchen Zhao"

Metallic Al has been deemed an ideal electrode material for aqueous batteries by virtue of its abundance and high theoretical capacity (8056 mAh cm). However, the development of aqueous Al metal batteries has been hindered by several side reactions, including water decomposition, Al corrosion, and passivation, which arise from the solvation reaction of Al and HO in conventional aqueous electrolytes. In this work, we report that water activity in electrolyte can be suppressed by optimizing the Al solvation structure through intercalation of polar pyridine-3-carboxylic acid in an aluminum trifluoromethanesulfonate aqueous environment.

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Constructing robust anode with strong aluminophilicity and rapid desolvation kinetics is essential for achieving high utilization, long-term durability, and superior rate performance in Al metal-based energy storage, yet remains largely unexplored. Herein, molybdenum nanoparticles embedded onto nitrogen-doped graphene (Mo@NG) are designed and prepared as Al host to regulate the deposition behavior and achieve homogeneous Al plating/stripping. The monodispersed Mo nanoparticles reduce the desolvation energy barrier and promote the deposition kinetics of Al.

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Objectives: To develop and validate a two-stage deep learning model for automatic detection and segmentation of brain metastases (BMs) in MRI images.

Methods: In this retrospective study, T1-weighted (T1) and T1-weighted contrast-enhanced (T1ce) MRI images of 649 patients who underwent radiotherapy from August 2019 to January 2022 were included. A total of 5163 metastases were manually annotated by neuroradiologists.

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The electrochemical performance of electrode materials is largely dependent on the structural and chemical evolutions during the charge-discharge processes. Hence, revealing ion storage chemistry could enlighten mechanistic understanding and offer guidance for rational design for energy storage materials. Here, we investigate the mechanisms of potassium (K)-ion storage in the promising bimetal oxide materials by magnetometry.

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Metal chalcogenide anodes with a layered structure have been regarded as potential K-based electrochemical energy storage devices with high energy density for large-scale energy storage applications. However, their development is impeded by the slow K-ion transport kinetics and poor structural stability. In this work, the energy-storage behavior is investigated first and decisively associated them with the capacity-degradation of the promising layer-structured WSe from an integrated chemical and physical point of view.

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Kidney cancer is one of the common cancers in the world. Automatic segmentation of the kidney and kidney tumor from CT images is of great significance for the therapy treatment of kidney cancer. Due to the diversity of the kidney tumor in terms of location, size, and shape, current methods have limited performance on the tumor segmentation, especially on the boundary.

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Sodium-ion capacitors (NICs) that have integrated the dual advantages of the high output of supercapacitors and the high energy density of batteries have stimulated growing attention for the next generation of practical electrochemical energy storage devices. The last years have seen the unprecedentedly rapid emergence of ilmenite materials, which present great promise in the realm of energy storage. However, NICs based on ilmenite materials have been scarcely researched so far.

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Owing to their low cost and abundant reserves relative to conventional lithium-ion batteries (LIBs), potassium-ion batteries (PIBs), and aluminum-ion batteries (AIBs) have shown appealing potential for electrochemical energy storage, but progress so far has been limited by the lack of suitable electrode materials. In this work, we demonstrated a facile strategy to achieve highly reversible potassium and aluminum ions storage in strongly coupled nanosized MoSe@carbon matrix, induced through an ion complexation strategy. We present a broad range of electrochemical characterization of the synthesized product that exhibits high specific capacities, good rate capability, and excellent cycling stability toward PIBs and AIBs.

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