Publications by authors named "Zhiyu Ren"

Ultra-broadband metamaterial absorbers can achieve near-perfect absorption of omnidirectional electromagnetic waves, crucial for light utilization and manipulation. Traditional ultra-broadband metamaterials rely on the superposition of different resonator units either in the plane or in perpendicular directions to broaden absorption peaks. However, this approach is subject to quantity restrictions and complicates the fabrication process.

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Ultrasensitive photoelectric detection of nitrogen dioxide (NO) with PHI under visible light irradiation at room temperature (RT) remains an ongoing challenge due to the low charge separation and scarce adsorption sites. In this work, a dimensionally matched ultrathin CoNiHHTP MOF/PHI Z-scheme heterojunction is successfully constructed by taking advantage of the π-π interactions existing between the CoNiHHTP MOF and PHI. The amount-optimized heterojunction possesses a record detection limit of 1 ppb (response = 15.

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Artificially designed metamaterial structures can manipulate electromagnetic waves, endowing them with exotic physical properties that are not found in natural materials, such as negative refractive index, superlens, and inverse Doppler effect. These characteristics are widely applied in various engineering and military applications. Due to increasingly complex application environments and innovation in radar detection technology, the combination of broadband absorption performance under thin thickness and efficient preparation methods at low cost is often the focus of research on new generation stealth materials.

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To improve the classification of pig vocalization using vocal signals and improve recognition accuracy, a pig vocalization classification method based on multi-feature fusion is proposed in this study. With the typical vocalization of pigs in large-scale breeding houses as the research object, short-time energy, frequency centroid, formant frequency and first-order difference, and Mel frequency cepstral coefficient and first-order difference were extracted as the fusion features. These fusion features were improved using principal component analysis.

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Traffic time series anomaly detection has been intensively studied for years because of its potential applications in intelligent transportation. However, classical traffic anomaly detection methods often overlook the evolving dynamic associations between road network nodes, which leads to challenges in capturing the long-term temporal correlations, spatial characteristics, and abnormal node behaviors in datasets with high periodicity and trends, such as morning peak travel periods. In this paper, we propose a mirror temporal graph autoencoder (MTGAE) framework to explore anomalies and capture unseen nodes and the spatiotemporal correlation between nodes in the traffic network.

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Although the electron-withdrawing effect of gold (Au) is highlighted in catalytic reactions, its enhancement mechanism for electron transport, especially in the electrochemical process, is still unclear. Herein, Au-decorated Bi O (Au-Bi O ) is proposed as a proof-of-concept to investigate the electron-withdrawing effect in the electrocatalytic CO reduction reaction (eCO RR) process. Evidence from in situ Raman spectra and in situ XRD tests reveals that, compared to Bi O , Bi species in Au-Bi O can be reduced to metallic Bi more rapidly and more easily driven by the electron-withdrawing effect of Au.

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The renewable electricity-driven hydrogen evolution reaction (HER) coupled with biomass oxidation is a powerful avenue to maximize the energy efficiency and economic feedback, but challenging. Herein, porous Ni-VN heterojunction nanosheets on nickel foam (Ni-VN/NF) are constructed as a robust electrocatalyst to simultaneously catalyze HER and 5-hydroxymethylfurfural electrooxidation reaction (HMF EOR). Benefiting from the surface reconstruction of Ni-VN heterojunction during the oxidation process, the derived NiOOH-VN/NF energetically catalyzes HMF into 2,5-furandicarboxylic acid (FDCA), yielding the high HMF conversion (>99%), FDCA yield (99%), and Faradaic efficiency (>98%) at the lower oxidation potential along with the superior cycling stability.

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The renewable-energy-driven integration of hydrogen production and biomass conversion into value-added products is desirable for the current global energy transition, but still a challenge. Herein, carbon-coated CoO-Co heterojunction arrays were built on copper foam (CoO-Co@C/CF) by the carbothermal reduction to catalyze the hydrogen evolution reaction (HER) coupled with a 5-hydroxymethylfurfural electrooxidation reaction (HMFEOR). The electronic modulation induced by the CoO-Co heterojunction endows CoO-Co@C/CF with a powerful catalytic ability.

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This study aimed to improve the transdermal permeation quantity of Baimai Ointment by investigating the enhancing effects of physical and chemical permeation promoting methods on transdermal permeation of Baimai Ointment. The improved Franz diffusion cell method was used for in vitro transdermal experiment. The abdominal skin of mice was used, and the skin was treated with 3% propylene glycol in the chemical enhancement group.

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Exquisite design of RuO -based catalysts to simultaneously improve activity and stability under harsh conditions and reduce the Ru dosage is crucial for advancing energy conversion involving oxygen evolution reaction (OER). Herein, a distinctive cobalt-doped RuO framework is constructed on Co O nanocones (Co O @CoRuO ) as a promising strategy to realize above urgent desires. Extensive experimental characterization and theoretical analysis demonstrate that cobalt doped in RuO lattice brings the oxygen vacancies and lattice contraction, which jointly redistribute the electron configuration of RuO .

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The "Fe effect" can maximize the activity of nickel-iron layered double hydroxides (NiFe-LDH) toward oxygen evolution reaction (OER) when the iron content, the lattice distortion, the conductivity, and other related factors are well balanced. It is difficult for the homogeneous NiFe-LDH to take good care of the above requirements at the same time. Herein, we proposed an elaborate atmosphere corrosion strategy to construct porous NiFe-LDH with rich edge/surface-Fe defects on Ni foam (NF).

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The electro-Fenton oxidation is one of the powerful approaches for achieving the complete mineralization of organic pollutants in water. The key dilemma for efficient industrial application of electro-Fenton oxidation is the complicated post-processing of iron sludge, and the cost and risk associated with HO transportation and storage. Herein, Cu-coupled Fe/FeC covered with carbon layer on carbon felt (Cu-Fe/FeC@C), engineered by a hydrothermal reaction followed by the consequent thermal-treatment in N atmosphere, as a self-supported integrated cathode were used for an onsite oxygen reduction reaction and a Fenton oxidation reaction.

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Although the activity of electrocatalysts towards oxygen evolution reaction (OER) has achieved considerable improvement by modulating the intrinsic electron structure, the role of supports to OER performance, often being reduced to enhancing the conductivity, is not fully explored. In this paper, a proof-of-concept study based on a series of hybrids of nickel iron (hydr)oxide nanoparticles (NiFeO NPs) and carbon supports with different oxidation level compared the motivation of supports for OER activity. The key to implementation lay in anchoring and growing of NiFeO NPs on the various carbon supports by electrostatic assembly and subsequent in-situ reduction.

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Efficient charge separation and rapid interfacial reaction kinetics are crucial factors that determine the efficiency of photocatalytic hydrogen evolution. Herein, a fascinating 2D heterojunction photocatalyst with superior photocatalytic hydrogen evolution performance - holey CN nanosheets nested with TiO nanocrystals (denoted as HCN/TiO) - is designed and fabricated via an in situ exfoliation and conversion strategy. The HCN/TiO is found to exhibit an ultrathin 2D heteroarchitecture with intimate interfacial contact, highly porous structures and ultrasmall TiO nanocrystals, leading to drastically improved charge carrier separation, maximized active sites and the promotion of mass transport for photocatalysis.

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Even though transition-metal phosphides (TMPs) have been developed as promising alternatives to Pt catalyst for the hydrogen evolution reaction (HER), further improvement of their performance requires fine regulation of the TMP sites related to their specific electronic structure. Herein, for the first time, boron (B)-modulated electrocatalytic characteristics in CoP anchored on the carbon nanotubes (B-CoP/CNT) with impressive HER activities over a wide pH range are reported. The HER performance surpasses commercial Pt/C in both neutral and alkaline media at large current density (>100 mA cm ).

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Nanostructure engineering of heteroatom-doped carbon catalysts can greatly enhance their electrocatalytic activity by increasing the accessible active sites and beneficial physical properties (e.g., surface area, conductivity, etc.

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The doping amount of heteroatoms in N, S co-doped carbon nanotubes (CNT-NS) was accurately and extensively regulated by retarding pyrolysis-gas diffusion. The effect of the content of N and S on the hydrogen evolution activity of CNT-NS was revealed for the first time both experimentally and theoretically.

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Electrochemical conversion of CO into syngas, which can be used directly in the classical petroleum industrial processes, provides a powerful approach for achieving the recycling of anthropogenic carbon. Pd has previously been reported to be capable of converting CO into syngas with various CO/H ratios, but only at limited applied potential, which is mainly attributed to fewer active sites exposed toward electrocatalysis. Herein, high-performance Pd nanomeshes (NMs) assembled with branch-like Pd nanoparticles were designed and synthesized by using a simple interface-induced self-assembly strategy; these NMs could catalyze CO -into-syngas conversion with a high current density in a wide applied potential range from -0.

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Electrochemical oxygen evolution reaction (OER) can be accelerated by employing transition-metal-based catalysts to obtain the desired activity and durability. Considering the promoting effect of the electrode structure on catalyzing OER, a stereo-film on carbon cloth comprising FeNi3 nanosheet-covered FeOOH (F@FeNi3-CC) was engineered by the hydrothermal reaction and subsequent synchronous electrodeposition of Fe and Ni ions. In F@FeNi3-CC, the FeOOH array not only provides the Fe source of FeNi3 nanosheets during the cathodic electrodeposition, but also functions as the support for the ultrathin FeNi3 nanosheets.

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Fabricating cost-effective, bifunctional electrocatalysts for both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in basic media is critical for renewable energy generation. Here, NiSe/CP, Ni Se/CP, and NiSe-Ni Se/CP heterostructure catalysts with different phase constitutions are successfully prepared through in situ selenylation of a NiO nanoflake array oriented on carbon paper (CP) by tuning the original Ni/Se molar ratio of the raw materials. The relationship between the crystal phase component and electrocatalytic activity is systematically studied.

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A simple and feasible strategy was reported to construct NiP nanostructures entwined by graphite layers (NiP/GC). In this process, a commercial amino phosphonic acid chelating resin was adopted as both the phosphorus and carbon resources. Then, Ni was introduced into the resin framework via ionic exchange and chelation to form a resin-Ni precursor.

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The development of effective approaches for preparing large-area, self-standing, ultrathin metal-based nanosheets, which have proved to be favorable for catalytic applications such as water electrolysis, is highly desirable but remains a great challenge. Reported herein is a simple and versatile strategy to synthesize ultrathin Co O and CoP NSs consisting of close-packed nanoparticles by pyrolyzing cobalt(II) phthalocyanine/graphene oxide (CoPc/GO) assemblies in air and subsequent topotactic phosphidation while preserving the graphene-like morphology. The strong π-π stacking interactions between CoPc and GO, and the inhibiting effect of the tetrapyrrole-derived macrocycle for grain growth during the catalytic carbon gasification contribute to the NSs forming.

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Gaining insight into the structure evolution of transition-metal phosphides during anodic oxidation is significant to understand their oxygen evolution reaction (OER) mechanism, and then design high-efficiency transition metal-based catalysts. Herein, NiCoP nanowires (NWs) vertically grown on Ni foam were adopted as the target to explore the in-situ morphology and chemical component reconstitution during the anodic oxidation. The major factors causing the transformation from NiCoP into the hierarchical NiCoP@CoNi(OOH) NWs are two competing reactions: the dissolution of NiCoP NWs and the oxidative re-deposition of dissolved Co and Ni ions, which is based primarily on the anodic bias applied on NiCoP NWs.

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Manipulating the electrical conductivity and morphology of Co-based (hydr)oxides is significant for optimizing energy conversion in the oxygen evolution reaction (OER). Herein, 2D CoSe nanocrystalline-dotted porous CoCo layered double hydroxide nanosheets (Co-Se NSs) were designed and synthesized via a modified in situ reduction and interface-directed assembly in an inert atmosphere. During the synchronous reduction/precipitation reaction between Co-oleylamine and NaHSe at the toluene-water interface, the hydrated Co-O and Co-Se clusters are generated and sequentially assemble under strong extrusion driven by the interfacial tension.

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This article aims to compare the qualities of Armeniacae Semen Amarum before and after rancidness, in order to study the rancidness of Armeniacae Semen Amarum. In the experiment, content of fatty oil, acid value and peroxide value were determined before and after rancidness,respectively. Meanwhile, HPLC, GC-MS were utilized to analyze laetrile and fatty acid components.

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